We present a study of Andreev Quantum Dots (QDots) fabricated with small-diameter (30 nm) Si-doped InAs nanowires where the Fermi level can be tuned across a mobility edge separating localized states from delocalized states. The transition to the insulating phase is identified by a drop in the amplitude and width of the excited levels and is found to have remarkable consequences on the spectrum of superconducting SubGap Resonances (SGRs). While at deeply localized levels, only quasiparticles co-tunneling is observed, for slightly delocalized levels, Shiba bound states form and a parity changing quantum phase transition is identified by a crossing of the bound states at zero energy. Finally, in the metallic regime, single Andreev resonances are observed.In superconductor-QDot-superconductor structures or at impurities in bulk superconductors, Bogoliubov type bound states can form at energy smaller than the superconducting gap energy ∆, leading to SGRs.The SGR formation depends on the different energy scales: ∆, the coupling Γ S of the QDot with the superconducting electrodes, the charging energy, U, and the energy, ε 0 , of the QDot level relative to the Fermi energy of the superconducting electrodes. Its phase diagram has been extensively studied theoretically [1,2]. For large coupling Γ S , the SGRs result from the coherent superposition of multiple Andreev reflections [3,4] and conductance peaks are expected at voltage values ∆/ne [5] where n is the number of Andreev reflections. For weak coupling Γ S , where the system is in the regime of Coulomb blockade, the ground state, singlet |S or doublet |D , results from the competition between the Kondo screening and the superconducting pairing interaction. These two ground states are separated by a parity changing quantum phase transition, which can be identified by the crossing of the SGRs at zero-energy. Previous works have addressed this transition through measurements of Josephson supercurrents [6][7][8][9][10] and studies of the SGRs in S-QDot-S [11][12][13][14][15][16][17] or N-QDot-S geometries [18][19][20][21]. Recently, similar devices attracted intense interest with the observation of the zero-energy Majorana end states in proximitized nanowires [22][23][24].The physics of odd parity QDot is related to the physics of Shiba states [25][26][27][28][29] forming at magnetic impurities in bulk superconductors, where tuning the magnetic exchange also leads to a parity changing quantum phase transition [30][31][32][33][34][35][36] [45]. In this work, we present an observation of Shiba bound states forming in a dopantinduced impurity band. In this diffusive regime, it is expected that an Anderson-like Metal-Insulator Transition (MIT) [46] separates the metallic regime at high carrier concentration from an insulating regime at low carrier concentration, where the localized and delocalized states in the band structure are separated in energy by a mobility edge. We identified this mobility edge in the conductance spectrum measured as function of gate voltage and sho...