In
this work, high-performance amorphous In0.75Ga0.23Sn0.02O (a-IGTO) transistors
with an atomic layer-deposited Al2O3 dielectric
layer were fabricated at a maximum processing temperature of 150 °C.
Hydrogen (H) and excess oxygen (Oi) in the Al2O3 film, which was controlled by adjusting the oxygen
radical density (PO2: flow rate of O2/[Ar+O2]) in the radio-frequency (rf) plasma during ALD growth of
Al2O3, significantly affected the performance
and stability of the resulting IGTO transistors. The concentrations
of H and Oi in Al2O3/IGTO stacks
according to PO2 were characterized by secondary ion mass
spectroscopy, X-ray photoelectron spectroscopy, hard X-ray photoemission
spectroscopy, and thermal desorption spectroscopy. The high concentration
of H at a low PO2 of 2.5% caused heavy electron doping
in the underlying IGTO during thermal annealing at 150 °C, leading
to a conductive behavior in the resulting transistor without modulation
capability. In contrast, a high PO2 condition of 20% introduced
O2 molecules (or Oi) into the Al2O3 film, which negatively impacted the carrier mobility
and caused anomalous photo-bias instability in the IGTO transistor.
Through in-depth understanding of how to manipulate H and Oi in Al2O3 by controlling the PO2, we fabricated high-performance IGTO transistors with a high field-effect
mobility (μFE) of 58.8 cm2/Vs, subthreshold
gate swing (SS) of 0.12 V/decade, threshold voltage
(V
TH) of 0.5 V, and I
ON/OFF ratio of ∼109 even at the maximum
processing temperature of 150 °C. Simultaneously, the optimized
devices were resistant to exposure to external positive gate bias
stress (PBS) and negative bias stress (NBS) for 3600 s, where the V
TH shifts for exposure to PBS and NBS for this
duration were 0.1 V and −0.15 V, respectively.