Epitaxial CuInSe2 thin films grown by molecular beam epitaxy and migration enhanced epitaxy

Abstract

While CuInSe 2 chalcopyrite materials are mainly used in their polycrystalline form to prepare thin film solar cells, epitaxial layers have been used for the characterization of defects. Typically, epitaxial layers are grown by metal-organic vapor phase epitaxy or molecular beam epitaxy (MBE). Here we present epitaxial layers grown by migration enhanced epitaxy (MEE) and compare the materials quality to MBE grown layers. CuInSe 2 layers were grown on GaAs (001) substrates by co-evaporation of Cu, In, and Se using substrate temperatures of 450 ºC, 530 ºC, and 620 ºC. The layers were characterized by high resolution X-ray diffraction (HR-XRD), highresolution transmission electron microscopy (HRTEM), Raman spectroscopy, and atomic force microscopy (AFM). HR-XRD and HR-TEM show a better crystalline quality of the MEE grown layers, and Raman scattering measurements confirm single phase CuInSe 2. AFM shows the previously observed faceting of the (001) surface into {112} facets with trenches formed along the [110] direction. The surface of MEE-grown samples appears smoother compared to MBEgrown samples, a similar trend is observed with increasing growth temperature.