Pyroxenes ((Ca, Mg, Fe, Mn) 2 Si 2 O 6 ) belong to the most abundant rockforming minerals that make up the surface of rocky planets and moons. Therefore sputtering of pyroxenes by solar wind ions has to be considered as a very important process for modifying the surface of planetary bodies. In order to quantify this effect, sputtering of wollastonite (CaSiO 3 ) by He 2+ ions, which are seen as a very prominent contribution to solar wind potential sputtering, was investigated. Thin films of CaSiO 3 deposited on a quartz crystal microbalance were irradiated allowing precise in-situ real time sputtering yield measurements. Experimental results were compared with simulations with the code SDTrimSP, which were improved by adapting the used surface binding energy.On a freshly prepared surface He 2+ ions show a significant increase in sputtering compared to equally fast He + ions. The yield, however, decreases exponentially with fluence, reaching steady state at considerably lower values after sputtering of the first few monolayers.Experiments using Ar 8+ ions show a similar behavior and are qualitatively explained by a preferential depletion of surface oxygen due to potential sputtering. A corresponding quantitative model is applied, which is able to reproduce the observed potential sputtering behavior of both He and Ar very well. The results of these calculations support the assumption that mainly O atoms are affected by potential sputtering. We conclude that the defect-mediated model of potential sputtering is also well-suited for CaSiO 3 .