The bonding configuration of a silicon host lattice in a carbon-induced partially relaxed pseudomorphic epilayer of SiGe is studied using x-ray photoelectron spectroscopy, high-resolution XRD and Raman spectroscopic techniques. In-plane and out-of-plane strains are estimated using high-resolution x-ray diffraction. Careful analysis of the x-ray photoelectron spectra (XPS) suggests that the bonding environment of the silicon host lattice is modified, and is attributed to the presence of graphite-like-sp 2 bonding in addition to the tetrahedral-sp 3 bonding. These results are further supported by our Raman studies. Our Raman studies indicate the presence of the BC-8 phase; a high-pressure phase of silicon. The modified configuration of the silicon host lattice at high pressure is responsible for the observed changes in the XPS and Raman spectra. These results are also compared with the carbon incorporated silicon epilayers (Si 1−x C x ) having negligible strain relaxation. We attribute these effects to the strain-induced effects and not to the compositional effects of Ge.