2016
DOI: 10.1142/s1793292016500752
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High-Performance Supercapacitor Based on the NaOH Activated D-Glucose Derived Carbon

Abstract: In this work, a mechanism of catalytic graphitization of D-glucose derived carbon during NaOH activation process is disclosed. The catalytic graphitization is caused by sodium atom, which is produced in the reaction between NaOH and carbon. Due to the combined action of activation and catalytic graphitization resulting from the NaOH, the activated D-glucose derived carbon behaves as a hierarchical micro-and meso-porous structure and has high electrical conductivity. Electrochemical investigations demonstrate t… Show more

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Cited by 13 publications
(2 citation statements)
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“…The voltage–time curves of the NPC are close to a linear shape, implying an outstanding electrical performance. The specific capacitance of the NPC-950-60 electrode calculated from the slope of the discharge curve was about 156 F g –1 at 0.1 A g –1 , which is higher than those of some other activated porous carbon materials. Meanwhile, as shown in Figure c, there is still a specific capacitance of 135 F g –1 after the current density increases 50-fold (5 A g –1 ), which is equivalent to 87% capacitance retention, indicating its good rate capability. Additionally, the galvanostatic charge–discharge curves of the NPC-950-30, NPC-950-100, NPC-900-100, NPC-850-30, activated polypyrrole powder, and cPPA at different current densities (0.1–5 A g –1 ) are displayed in Figure S9.…”
Section: Resultsmentioning
confidence: 92%
“…The voltage–time curves of the NPC are close to a linear shape, implying an outstanding electrical performance. The specific capacitance of the NPC-950-60 electrode calculated from the slope of the discharge curve was about 156 F g –1 at 0.1 A g –1 , which is higher than those of some other activated porous carbon materials. Meanwhile, as shown in Figure c, there is still a specific capacitance of 135 F g –1 after the current density increases 50-fold (5 A g –1 ), which is equivalent to 87% capacitance retention, indicating its good rate capability. Additionally, the galvanostatic charge–discharge curves of the NPC-950-30, NPC-950-100, NPC-900-100, NPC-850-30, activated polypyrrole powder, and cPPA at different current densities (0.1–5 A g –1 ) are displayed in Figure S9.…”
Section: Resultsmentioning
confidence: 92%
“…The C sp value of the electrode was computed as 12.9 F g −1 with a CD of 0.5 A g −1 . Likewise, Wu et al 15 developed a graphitization process of D-glucose-derived carbon by NaOH activation at elevated temperatures (600−900 °C). A maximum SSA of 1310 m 2 g −1 yields a high C sp of 106 F g −1 in the 6.0 M KOH electrolyte and retains 70% capacity retention at a scan rate of 2.0 V s −1 , which provides a low-cost technique for synthesizing high-performance electrode materials for SCs.…”
Section: Introductionmentioning
confidence: 99%