Highly dispersed Co/SBA-15 mesoporous materials as efficient and stable catalyst for partial oxidation of cyclohexane with molecular oxygen

Non Noble-Metal Copper–Cobalt Bimetallic Catalyst for Efficient Catalysis of the Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions

“…The high-resolution spectrum of Cu 2p (Figure c) shows a peak of Cu 2p 3/2 near 934 eV, which is decomposed into two peaks at 934.1 and 932.2 eV, corresponding to Cu 2+ and Cu 0 /Cu + , respectively. − The ratio of the peaks of Cu + /Cu 0 and Cu 2+ has been calculated and shown in Table S2. Similarly, in the Auger spectrum of Cu LMM (Figure d), peaks at 913.1, 917.1, and 920.8 eV correspond to Cu + , Cu 2+ , and Cu 0 , respectively. , The doublet separation between the 2p 3/2 and 2p 1/2 signals approaches 15.5 eV (Figure b), which agrees with the standard spectra of elemental cobalt, suggesting the existence of Co 3+ or Co 2+ species . The satellite peak at 789.6 eV corresponds to Co 2+ , and the peaks at 785.2 and 780.5 eV correspond to the binding energies of Co 2+ and Co 3+ , respectively, indicating that cobalt exists mainly in the form of oxides. − …”

Catalytic pyrolysis of coconut oil with Ni/SBA-15 for the production of bio jet fuel

“…5(c–f) ) the appearance of glittering particles on the support is noted, which are considered to belong to nickel metal. 60 This behavior was also reported by Erdogan and collaborators. 61 On the other hand, it is clear that there were no significant morphological changes in the catalytic support after the insertion of different percentages of nickel metal and subsequent heat treatment.…”

Solvent-free liquid-phase selective catalytic oxidation of toluene to benzyl alcohol and benzaldehyde over CeO2–MnOx composite oxides

“…To date, few research studies on Ce-Mn composite oxides have been reported in solvent-free liquid-phase selective catalytic aerobic oxidation of toluene. Based on this concept and our previous studies of the oxidation reaction, [32][33][34][35][36] a simple and environmentally friendly approach for selective preparation of BAL and BOL from the liquid-phase aerobic oxidation of toluene in a solvent-free system has been successfully developed employing CeO 2 -MnO x composite oxides as an efficient and cheap catalyst. The obtained results from the catalytic aerobic oxidation process of toluene will be reported in detail in the present work.…”