1953
DOI: 10.1002/cber.19530861023
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tert.‐Butylbutadien und Acrylsäure (Ein Beitrag zur Kenntnis der Dien‐Synthese mit unsymmetrischen Addenden)

Abstract: Alder, Heimbach, Kuhle:[Jahrg. 86 _^_ _ .-~ . _ _ _~. . _ _~_ _ _ _ _ _ _ schmolzen bei 167O (korr.); Ausb. etwa 0.02.g. Die Substanz loste sich in konz. Schwefelsiiure mit blauviolettar Farbe. Der Miech-Schmelzpunkt mit dem D i a c e t a t des 2. Wiihrend bei den bisher untersuchten 1-substituierten Butadienen die Addition von Acrylsiiure praktisch ausschlieBlich zu Addukten mit ortho-standigen Substituenten fiihrt, ergibt das 1-tert.-Butylbutadien neben dem normalen ortho-Addukt auch die mefu-Form in priipar… Show more

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Cited by 8 publications
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“…The combined organic layers were washed with brine (25 mL), dried, and concentrated. Upon distillation, no trace of 5,5-dimethyl-1,3-hexadiene was obtained (its boiling point was supposed to be 106 ± 107 8C/760 Torr [66] ). Instead, the title product was collected as a colorless liquid which, according to 1 Tris(2-hydroxyphenyl)phosphine oxide: Hydrochloric acid (6 m, 25 mL) was added to a solution of tris(2-methoxymethoxyphenyl)phosphine oxide (11.5 g, 25 mmol) in tetrahydrofuran (100 mL).…”
Section: -Methyl-2-butenyltris(2-methoxymethoxyphenyl)phosphonium Brmentioning
confidence: 99%
“…The combined organic layers were washed with brine (25 mL), dried, and concentrated. Upon distillation, no trace of 5,5-dimethyl-1,3-hexadiene was obtained (its boiling point was supposed to be 106 ± 107 8C/760 Torr [66] ). Instead, the title product was collected as a colorless liquid which, according to 1 Tris(2-hydroxyphenyl)phosphine oxide: Hydrochloric acid (6 m, 25 mL) was added to a solution of tris(2-methoxymethoxyphenyl)phosphine oxide (11.5 g, 25 mmol) in tetrahydrofuran (100 mL).…”
Section: -Methyl-2-butenyltris(2-methoxymethoxyphenyl)phosphonium Brmentioning
confidence: 99%