1997
DOI: 10.1016/s0376-7388(96)00185-8
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Limiting current density and water dissociation in bipolar membranes

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Cited by 322 publications
(239 citation statements)
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“…4. Obviously, the experimental I -V curves for the three configurations show the typical behavior given by the coupling of ion transport and electrical field-enhanced water dissociation [14], at small voltage, the current is carried mainly by decreases with time, which conforms to the typical trends. At a given time, the current efficiency decrease with increase in the concentration of sodium citrate, as in the case of 0.1, 0.5, 1 M sodium citrate solutions, thereby restricting the possibility of obtaining high concentration of acid and alkali [8].…”
Section: Current-6oltage Cur6essupporting
confidence: 70%
“…4. Obviously, the experimental I -V curves for the three configurations show the typical behavior given by the coupling of ion transport and electrical field-enhanced water dissociation [14], at small voltage, the current is carried mainly by decreases with time, which conforms to the typical trends. At a given time, the current efficiency decrease with increase in the concentration of sodium citrate, as in the case of 0.1, 0.5, 1 M sodium citrate solutions, thereby restricting the possibility of obtaining high concentration of acid and alkali [8].…”
Section: Current-6oltage Cur6essupporting
confidence: 70%
“…To avoid the water splitting in BMs one can introduce a neutral electrolyte gap between the two membranes 34, [39][40][41][42] . Recently, this strategy was employed in ion bipolar junction transistors (IBJTs) 22 .…”
mentioning
confidence: 99%
“…Cation-and anion-selective membranes are in many aspects the ionic equivalent to p-and ndoped semiconductors, respectively. By sandwiching a cationand an anion-selective membrane a bipolar membrane (BM) is obtained [9][10] . BMs exhibit current rectification in similarity to bipolar semiconductor pn-junction diodes.…”
mentioning
confidence: 99%