In this work we point out experimentally the anomalous behavior of the total mobility as a function of temperature for a specified doped n-Ge sample. Three perfect Ge crystals were grown, with As and Ga as donor and acceptor impurities, with suitable concentrations in one of the crystals, in order to satisfy the condition which is imposed by a theoretical model e.g. 5 × 10 −2 < N A /N D < 0.33 and N D + N A > 8 × 10 13 cm −3 . Therefore for this specified crystal the mobility reaches at T = 9 K a maximum, at T = 23 K it reaches a minimum, at T = 25 K it increases according to T −3/2 law, and then decreases monotonously according to T −3/2 law due to the phonon scattering. In contrast in the other two samples, the mobilities first increase monotonously and then at 18 K and at 26 K decrease monotonously due to the T −3/2 law.