Multiresidue analytical method for the determination of antimicrobials, preservatives, benzotriazole UV stabilizers, flame retardants and plasticizers in fish using ultra high performance liquid chromatography coupled with tandem mass spectrometry

Kim, Joon‐Woo; Ramaswamy, Babu Rajendran; Chang, Kwang‐Hyeon; Isobe, Takeshi; Tanabe, Shinsuke

doi:10.1016/j.chroma.2011.04.006

Cited by 135 publications

(65 citation statements)

References 47 publications

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“…13,14 It was reported that bioaccumulation factors (BAFs) were found to be as high as 2100 for TCS and 2700 for TCC in algae. 15 Hence, the extensive detection of TCS and TCC has become a public concern as they may affect aquatic organisms such as algae, 16 crustacean 17 and sh.…”

Section: 12mentioning

confidence: 99%

Multimedia modeling of the fate of triclosan and triclocarban in the Dongjiang River Basin, South China and comparison with field data

Zhang

Zhao

Liu

et al. 2013

Environ. Sci.: Processes Impacts

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Triclosan (TCS) and triclocarban (TCC) are two active ingredients widely used in many home and personal care products. Multimedia fate of TCS and TCC in the Dongjiang River basin, South China were addressed by the developed level III fugacity model based on their usage. Under the assumption of steady state, the concentrations in air, water, soil, sediment, suspended particulate matter (SPM) and fish as well as transfer flux across the interface between the compartments were simulated. The measured concentrations for the two compounds in water, SPM, and sediment from field monitoring campaigns were then compared to validate the model. The results showed that the model predicted reasonably accurate concentrations and the differences between the measured and modeled concentrations were all less than 0.7 log units. TCS and TCC had a tendency to distribute into the sediment phase, which accounted for more than 66.3% and 90.3% of the total masses, respectively. Wastewater discharge was the main source for the occurrence of the two compounds in the aquatic environment, while degradation was the primary process for the loss in the study area, followed by the advection export.Sensitivity analysis showed that the most influential parameters for the fate of the target chemicals were source term, degradation rates and adsorption coefficients. Monte Carlo simulation could well describe the modeling uncertainty and variability. Environmental impactPersonal care products are widely used in everyday life. Aer use, they are discharged into the receiving environments directly or indirectly. Their detection in the environment has become an increasing concern due to their potential impacts on the ecosystem. This paper developed a modied level III fugacity model to assess the multimedia fate of two personal care products (triclosan and triclocarban) in a river basin based on their usage data and evaluated the model by eld monitoring data in the Dongjiang River Basin. The modied steady state fugacity model can be used to evaluate contamination of personal care products at the basin scale based on their usage. This tool could be adopted by various decision-makers in the management of chemicals in river basins.

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Section: 12mentioning

confidence: 99%

Multimedia modeling of the fate of triclosan and triclocarban in the Dongjiang River Basin, South China and comparison with field data

Zhang

Zhao

Liu

et al. 2013

Environ. Sci.: Processes Impacts

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“…Scientists often used Soxhlet extraction (SE) with different , Johnson-Restrepo et al 2008, Ueno et al 2006, Xian et al 2008, Su et al 2014, Hu et al 2011, Lankova et al 2013, He et al 2013, Zhang et al 2013, Jeong et al 2014, Roosens et al 2008, Roosens et al 2010, Losada et al 2009, McHugh et al 2010. The advantage for this extraction was high recovery values but extraction time was quite long and ranged from 4 to 48 h. Some of the researchers also used classic solvent extraction; nevertheless, recovery values were not always high enough and the consumption of solvents was high (Nyholm et al 2008, Asante et al 2013, Kim et al 2011. Very popular in those kind of matrices was accelerated solvent extraction (ASE, PLE), which can lead to very high recovery values in a short time (Xia et al 2011, Haukas et al 2009, Feng et al 2010, Ilyas et al 2013, ten Dam et al 2012, Gao et al 2014, Sundkvist et al 2010.…”

Section: Introductionmentioning

confidence: 99%

“…In this paper, we focused on two brominated flame retardants (BFRs) that are widely used and produced in high amounts-(TBBPA) and (HBCD) and two organophosphate flame retardants (OPFRs)-EHDP and TPhP. The selection of OPFRs for this study was justified by the fact that these are quite new compounds that have been of researchers' interest in biological samples (Chen et al 2012, Kim et al 2011, Greaves et al 2016). …”

Section: Introductionmentioning

confidence: 99%

UAE-SPE-UHPLC-UV Method for the Determination of Flame Retardants in Fish Tissues

Kowalski

Płaszczyk

2017

Food Anal. Methods

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Analytical method for the determination of four flame retardants (FRs) from two groups was proposed. These groups included the brominated flame retardants (BFRs) 3,3′,5,5′-tetrabromobisphenol A (TBBPA) and 1,2,5,6,9,10-hexabromocyclododecane (HBCD); triester organophosphate flame retardants (OPFRs), ethylhexyl diphenyl phosphate (EHDP) and triphenyl phosphate (TPhP). Reversed-phase Ultra HPLC with a UV detector, Hypersil GOLD chromatographic column and two-eluent gradient elution programme was used to obtain the best separations within the shortest possible time. UAE extraction with acetone, ethyl acetate and acetone/ethyl acetate (1:1, v/v) solvents was proposed. For the removal of fats, addition of sulphuric acid (VI) was conducted as well as solid-phase extraction (SPE) for the final clean-up of the extracts was used. The best recoveries were achieved with acetone/ethyl acetate (1:1, v/v) mixture of solvents and Bond Elut ENV column for SPE step gave the highest overall recoveries. Method detection limits (MDL) ranged from 0.05 to 0.39 μg g −1 and method quantification limits (MQL) ranged from 0.15 to 1.16 μg g −1 for all compounds.

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“…Estudos recentes relatam a importância do desenvolvimento de novos métodos com o propósito de analisar parabenos, mesmo que em baixas concentrações, em matriz biológica tal como, o peixe e com isso obter dados relevantes que possam relatar níveis de contaminação dos rios e oceanos (JAKIMSKA et al, 2013;SUBEDIA et al,2011;KIM et al, 2011 O detector com arranjo de diodos é um detector amplamente utilizado na cromatografia líquida atualmente, por ser considerado seletivo, uma vez que a substância precisa absorver luz; possuem mecanismos de operação bem estabelecidos, limites de detecção apropriados, são compatíveis com gradientes de eluição, pouco sensíveis a mudanças na temperatura e possuem boa sensibilidade (LANÇAS,2009).…”

Section: Métodos Analíticosunclassified

“…A Tabela (KIM et al, 2011;SUBEDI et al,2011;SUBEDI et al,2011) e coeficiente de determinação compatível com o detector utilizado, como apresentado na Tabela 9.…”

Section: Exatidão E Precisãounclassified

Desenvolvimento e validação de método analítico para análise de parabenos em tecido de peixes

Ribeiro¹

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Multiresidue analytical method for the determination of antimicrobials, preservatives, benzotriazole UV stabilizers, flame retardants and plasticizers in fish using ultra high performance liquid chromatography coupled with tandem mass spectrometry

Cited by 135 publications

References 47 publications

Multimedia modeling of the fate of triclosan and triclocarban in the Dongjiang River Basin, South China and comparison with field data

Multimedia modeling of the fate of triclosan and triclocarban in the Dongjiang River Basin, South China and comparison with field data

UAE-SPE-UHPLC-UV Method for the Determination of Flame Retardants in Fish Tissues

Desenvolvimento e validação de método analítico para análise de parabenos em tecido de peixes

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