2007
DOI: 10.1016/j.diamond.2006.12.029
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Nano- and micro-crystalline diamond growth by MPCVD in extremely poor hydrogen uniform plasmas

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Cited by 31 publications
(17 citation statements)
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“…into two sub-bands, one at 1475 cm -1 and the other at about 1550 cm -1 , both identified by peak fitting, assigned to trans-polyacetylene (TPA), and the G band of graphitic materials [21], respectively. The weak band visible at 1140 cm -1 appearing in samples grown at higher power (3.5 kW and 4.0 kW) with slightly higher amounts of N 2 , confirm the presence of TPA at the grain boundaries, together with the 1475 cm -1 band [22]. It is worth to note that TPA is not intrinsic to diamond, but has been commonly found as a non-diamond impurity phase coexisting in most NCD films grown by CVD methods.…”
Section: Methodssupporting
confidence: 59%
“…into two sub-bands, one at 1475 cm -1 and the other at about 1550 cm -1 , both identified by peak fitting, assigned to trans-polyacetylene (TPA), and the G band of graphitic materials [21], respectively. The weak band visible at 1140 cm -1 appearing in samples grown at higher power (3.5 kW and 4.0 kW) with slightly higher amounts of N 2 , confirm the presence of TPA at the grain boundaries, together with the 1475 cm -1 band [22]. It is worth to note that TPA is not intrinsic to diamond, but has been commonly found as a non-diamond impurity phase coexisting in most NCD films grown by CVD methods.…”
Section: Methodssupporting
confidence: 59%
“…The 1140 and 1480 cm −1 shoulders, usually attributed to trans‐polyacetylene, are an indirect proof of the presence of NCD 28, 29. A band at 1228 cm −1 is also visible that appeared to be conjugated with vibration modes of C‐H chains characteristic of nano‐ and ultrananocrystalline diamond 30. Furthermore, it is also visible the 1332 cm −1 diamond band as well as the D (1360 cm −1 ) and G (1560 cm −1 ) graphite bands.…”
Section: Resultsmentioning
confidence: 95%
“…The characteristics of diamond is present at 1332 cm −1 . 17,19 Three peaks at 1130, 1192, and 1458 cm −1 derive from the nanocrystals, 19,20 which is induced by the C−H bonds at grain boundaries of nanocrystals. All the nanotwins are along the same orientation, reaching a length to several micrometers.…”
mentioning
confidence: 99%