We have employed ballistic electron emission microscopy ͑BEEM͒ to study the energy positions in the conduction band of Al x Ga 1Ϫx As. Epilayers of undoped Al x Ga 1Ϫx As were grown by molecular beam epitaxy on conductive GaAs substrates. The Al composition x took on values of 0, 0.11, 0.19, 0.25, 0.50, 0.80 and 1 so that the material was examined in both the direct and indirect band gap regime. The Al x Ga 1Ϫx As layer thickness was varied from 100 to 500 Å to ensure probing of bulk energy levels. Different capping layers and surface treatments were explored to prevent surface oxidation and examine Fermi level pinning at the cap layer/Al x Ga 1Ϫx As interface. All samples were metallized ex situ with a 100 Å Au layer so that the final BEEM structure is of the form Au/capping layer/Al x Ga 1Ϫx As/bulk GaAs. Notably we have measured the Schottky barrier height for Au on Al x Ga 1Ϫx As. We have also probed the higher lying band edges such as the X point at low Al concentrations and the L point at high Al concentrations. Variations of these critical energy positions with Al composition x were mapped out in detail and compared with findings from other studies. Local variations of these energy positions were also examined and found to be on the order of 30-50 meV. The results of this study suggest that BEEM can provide accurate positions for multiple energy levels in a single semiconductor structure.