Notizen: Zur Kenntnis eines Berylliumazids Be(N₃)₂

Abstract

Berylliumdimethyl reagiert mit Stickstoffwasserstoffsäure in ätherischer Lösung schon bei der Schmelztemperatur des Äthers (—116°) in heftiger Umsetzung unter Methanentwicklung und Bildung eines äther-unlöslichen, tetrahydrofuran-löslichen, in der Flamme nur schwach verpuffenden und sehr feuchtigkeits-empfindlichen Berylliumazids Be(N3)2: BeR2 + 2 HN3 → Be(N3)2 + 2 RH.

Lewis Base Adduct Stabilized Organogallium Azides: Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas

“…This corresponds well with the behavior of Ga(N 3 ) 3 and its N-base adducts. Ga(N 3 ) 3 , a white and insoluble solid, probably a coordination polymer, , detonates when heated suddenly above 300 °C or when attempts are made to sublime it at 180 °C and 10 -5 Torr and is also sensitive to intense shock. The respective monomeric N-base adducts Ga(N 3 ) 3 (L) n (L = NEt 3 , n = 1; L = py, n = 3) do not detonate upon heating or mechanical impact…”

“…It was shown, that the azide group serves as the major nitrogen source for the GaN growth. , Compared to this promising potential for various applications in microelectronics the chemistry of (organometallic) gallium azides seems to be still rather undeveloped 4,5 since the early work of Wiberg et al. on Ga(N 3 ) 3 and Dehnicke et al on [R 2 Ga(N 3 )] 3 …”

Electrodeposition of Magnesium and Beryllium from Organic Baths

“…Most of t h e subsequent experiments involved t h e r e a c t i o n of b e r y llium dimethyl w i t h various compounds and t h e e f f e c t of v a r i a t i o n of t h e s o l v e n t (Table I, No. [1][2][3][4][5][6][7][8][9][10][11][12][13][14]. I n t h e f u r t h e r search f o r an improved beryllium p l a t i n g process w e e l e c t r o l y z e d s o l u t i o n s of some d i f f e r e n t kinds of beryllium compounds, which had r e c e n t l y been prepared i n nonaqueous systems, such as t h e a z i d e and thiocyanate (No.…”

Theoretical study of the decomposition mechanism of a series of group III triazides X(N3)3 (X = B, Al, Ga)

“…The results show that the decomposition of B(N 3 ) 3 takes place on either the singlet and triplet surface, and both processes are high exothermic and obey sequential mechanisms. The triazides of aluminum and gallium were synthesized for the first time in Wiberg's group from diethylether solutions of the respective hydrides EH3 and three equivalents of hydrazoic acid . These azides have been obtained as colorless solids, which were soluble in tetrahydrofuran.…”