2009
DOI: 10.1039/b901826c
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Organo-soluble photoresponsive azo thiol monolayer-protected gold nanorods

Abstract: Organo-soluble photoresponsive azo thiol monolayer-protected gold nanorods were synthesized; the resulting gold nanorods encapsulated by thiols on their entire surface with strong covalent Au-S linkages were very stable in both organic solvents and in the solid state without aggregation or decomposition.

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Cited by 52 publications
(47 citation statements)
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“…Ultraviolet-irradiation techniques have been used to synthesize metal NPs like Ag [5], Au [25], Pd [26] and semi-conductor wires [27] at significantly higher speed compared to conventional thermal convection methods. Recently, El Khoury et al reported that UV-irradiation technique could offers a simple and efficient method for the purification of gold nanorods from excess thiol surfactants in the solution [28] reports for the in situ synthesis of 1-D Ag nanowires by 8 min of UV-photoirradiation on PVA scaffolds in the presence of negatively charged Au seed particles.…”
Section: Introductionmentioning
confidence: 98%
“…Ultraviolet-irradiation techniques have been used to synthesize metal NPs like Ag [5], Au [25], Pd [26] and semi-conductor wires [27] at significantly higher speed compared to conventional thermal convection methods. Recently, El Khoury et al reported that UV-irradiation technique could offers a simple and efficient method for the purification of gold nanorods from excess thiol surfactants in the solution [28] reports for the in situ synthesis of 1-D Ag nanowires by 8 min of UV-photoirradiation on PVA scaffolds in the presence of negatively charged Au seed particles.…”
Section: Introductionmentioning
confidence: 98%
“…In addition, some functional molecules on the surface of GNPs could work as molecular ''glue'' to assemble nanostructures [89]. Various thiols have been applied to prepare functional GNRs [90][91][92][93]. GNRs assembling in specific patterns, including end-to-end and side-by-side fashions can exhibit unique collective properties which are different from those of both individual GNR and bulk materials [33,94,95].…”
Section: Hybrid Gold Nanorodsmentioning
confidence: 99%
“…For the organic thiol monolayer protected anisotropic AuNRs, the solubility, surface chemistry and related properties are dominated by the organic shell. Simple n-alkyl thiols [167], and other functional materials such as photoresponsive azo thiols [168], chiral-azo thiols [169], organic dyes (porphyrin, perylene) [159,160] and polymers terminated with thiols (poly2-(dimethylamino)ethyl methacrylate, poly(acrylic acid), polystyrene) have been used [170].…”
Section: Surface Modificationmentioning
confidence: 99%