Phosphorylation of Kraft fibers with phosphate esters

Shi, Ying; Belosinschi, Dan; Brouillette, François; Belfkira, Ahmed; Chabot, Bruno

doi:10.1016/j.carbpol.2014.01.070

Cited by 69 publications

(66 citation statements)

References 21 publications

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“…In the GeP 3 /C composite, the P-O and P=O peaks almost disappear but the additional P-O-C peak located at 1008 cm −1 is detected, which may be due to the residual oxygen formed by reduction reaction between GeO 2 and red phosphorus during the HEMM process ( Fig. 3a ) 30 36 43 . The high-resolution P 2p XPS spectrum in Fig.…”

Section: Resultsmentioning

confidence: 99%

Facile Synthesis of Layer Structured GeP3/C with Stable Chemical Bonding for Enhanced Lithium-Ion Storage

Zhao

et al. 2017

Sci Rep

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Recently, metal phosphides have been investigated as potential anode materials because of higher specific capacity compared with those of carbonaceous materials. However, the rapid capacity fade upon cycling leads to poor durability and short cycle life, which cannot meet the need of lithium-ion batteries with high energy density. Herein, we report a layer-structured GeP3/C nanocomposite anode material with high performance prepared by a facial and large-scale ball milling method via in-situ mechanical reaction. The P-O-C bonds are formed in the composite, leading to close contact between GeP3 and carbon. As a result, the GeP3/C anode displays excellent lithium storage performance with a high reversible capacity up to 1109 mA h g−1 after 130 cycles at a current density of 0.1 A g−1. Even at high current densities of 2 and 5 A g−1, the reversible capacities are still as high as 590 and 425 mA h g−1, respectively. This suggests that the GeP3/C composite is promising to achieve high-energy lithium-ion batteries and the mechanical milling is an efficient method to fabricate such composite electrode materials especially for large-scale application.

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Section: Resultsmentioning

confidence: 99%

Facile Synthesis of Layer Structured GeP3/C with Stable Chemical Bonding for Enhanced Lithium-Ion Storage

Zhao

et al. 2017

Sci Rep

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“…The peaks at 1,160 and 1,050 cm À1 can be assigned to P=O and P-O bonds as a result of the exposure of P nanoparticles in the air. 40 Notably, the peak centered at 1,008 cm À1 suggests the formation of a P-O-C bond, 41 also indicating the strong interaction between rGO, CNTs, and red P. To quantitatively evaluate the P content in the P/CNTs@rGO electrode, we conducted thermogravimetry (TG). As illustrated in Figure S4, the measured P content of 69.3 wt % is consistent with the feeding ratio of P (70 wt %), suggesting that red P can be efficiently trapped in the graphene network during the self-assembly process.…”

Section: Resultsmentioning

confidence: 99%

Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage

Jiang

Niu

Zhu

et al. 2018

Chem

135

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Red phosphorus (P), which has a high theoretical specific capacity ($2,600 mA hr g À1), low cost, and commercial availability, has been severely limited by large volume variation and poor electrical conductivity for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). Here, we fabricate a self-standing P/CNTs@rGO hierarchical structure to effectively resolve the critical issues associated with red P. The self-standing P/CNTs@rGO electrode achieves an unprecedented capacity and thus represents an advanced step toward high-performance P-based anodes for LIBs and SIBs.

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“…e evaluation of a new antibacterial paper, silver phosphorylated cellulose fibers, as an innovative way to deliver silver ions rapidly and efficiently in in vitro conditions on planktonic Staphylococcus aureus was our goal. Compared with commercial products which sustained release of silver ions at the wound surface from ionic reactions to solubilized AgNO 3 by wound exudate or moisture of the skin (fluid) and oxygen, SPCF, by its innovative way to incorporating ionic silver, released bactericidal components immediately at the contact area [27,35]. is presentation maximizes rapid response for bacteria killing while minimizing survival rates and the emergence of mutation and resistance [40].…”

Section: Discussionmentioning

confidence: 99%

“…e affinity of dressing to moisture also influences the bactericidal effect [27,53]. In the SPCF, the specific amount of silver ions can be calculated precisely (number of phosphorylated groups), which is interesting for maximizing antibacterial activity at lower silver concentration [29,35].…”

Section: Discussionmentioning

confidence: 99%

“…SPCF keeps their morphology from unmodified cellulose fibers, but mechanical and surface properties are different ( Figure 2). For example, SPCF strength properties are very low, but that can be compensated by mixing SPCF and unmodified cellulose fibers to keep its original properties with antibacterial properties [29,34,35]. SPCF samples had a brown color (see samples represented in Figure 3).…”

Section: Preparation Of Spcf Samplesmentioning

confidence: 99%

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New Antibacterial Paper Made of Silver Phosphate Cellulose Fibers: A Preliminary Study on the Elimination of Staphylococcus aureus Involved in Diabetic Foot Ulceration

Blanchette

Belosinschi

Lai

et al. 2020

BioMed Research International

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Aim. To evaluate in vitro the antibacterial effect of a paper made of silver phosphate cellulose fibers (SPCF) on Staphylococcus aureus, the most common diabetic foot ulceration (DFU) pathogen when compared with other common commercial products. Methods. The antibacterial activity of SPCF samples was evaluated through time with cell counting on agar plates. SPCF samples were then compared with commercial wound care products currently in use in DFU treatments (Silvercel™, Acticoat 7, and Aquacel Ag ExtraTM) through time on agar plates (growth inhibition zones). Results. After 6 hours, there was no viable bacterial cell detected on either plate (p<0.05). There was a net growth inhibition zone for SPCF samples but no significant difference between the two silver concentrations. Compared with common commercial products, SPCF paper provides results equal to Acticoat 7 (p<0.05) and superior to Aquacel AG ExtraTM and Silvercel™ at lower silver concentrations (p<0.001). Conclusions. These results have shown the efficiency of SPCF paper to eliminate Staphylococcus aureus in these conditions. SPCF papers are effective when compared with other common commercial products and could have an industrial potential in wound care. Infected DFU could benefit from the antibacterial effectiveness of SPCF, but more relevant experimentations related to foot ulcers are needed.

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Phosphorylation of Kraft fibers with phosphate esters

Cited by 69 publications

References 21 publications

Facile Synthesis of Layer Structured GeP3/C with Stable Chemical Bonding for Enhanced Lithium-Ion Storage

Facile Synthesis of Layer Structured GeP3/C with Stable Chemical Bonding for Enhanced Lithium-Ion Storage

Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage

New Antibacterial Paper Made of Silver Phosphate Cellulose Fibers: A Preliminary Study on the Elimination of Staphylococcus aureus Involved in Diabetic Foot Ulceration

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