Konjac
flour, mainly obtained and purified from the tubers ofAmorphophallus konjac C. Koch, yields a high molecular
weight (M
w) and viscous hydrocolloidal
polysaccharide: konjac glucomannan (KGM). KGM has been widely applied
in the food industry as a thickening and gelation agent as a result
of its unique colloidal properties of effective viscosity enhancement
and thermal-irreversible gelling. This review first narrates the typical
commercial KGM source species, the industrial production, and the
purification process of KGM flour. The structural information on native
KGM, gelation mechanisms of alkali-induced deacetylated KGM (Da-KGM)
hydrogel, progress on degraded KGM derivatives, cryoprotection effect,
and colloidal nutrition are highlighted. Finally, the regulatory requirements
of konjac flour and KGM among different countries are briefly introduced.
The fine structure and physicochemical properties of KGM can be regulated
in a great range via the deacetylation or degradation reaction. Here,
the relationship between the physicochemical properties, such as viscosity,
solubility, gelation, and nutritional effects, of native KGM, Da-KGM,
and degraded KGM derivatives was preliminary established, which would
provide theoretical guidance for designing KGM-based products with
certain nutritional needs.