Polyhydrochinonsulfone^1,2. III. Synthese einiger hydrochinonsulfone

Abstract

Einige Modellverbindungen und Vinylmonomere für Redoxpolymere wurden synthetisiert, in denen ein Hydrochinonkern oder methylsubstituierter Hydrochinonkern über eine Sulfonbrücke mit einem substituierten Benzolkern bzw. einer Chloräthyl‐ oder Vinylgruppe verknüpft ist.

Electron‐transfer polymers (oxidation‐reduction polymers)

“…A large number of model compounds in which hydroquinone groups and derivatives are linked through the -SO2-function, often as a substituent on other groups such as p-tolyl, have been prepared in in Manecke's laboratory (134,139).…”

“…Manecke and Beyer (136) have prepared dimers in which a hydroquinone molecule is bridged to a substituted aromatic nucleus with a sulphone linkage. This model study led to the synthesis of polyhydroquinonesulfones (134,137,138,169).…”