Preparation and properties of novel soluble poly(aryl ether)s bearing covalently bound tetrapyrazinoporphyrazine units

Abstract

SYNOPSIS Thennooxidatively stable amorphous poly (dicyanopyrazine ether) s with high glass transition temperatures are synthesized and converted into poly ( aryl ether) s bearing covalently bound zinc (11) 2,3,9,10,16,17,23,24-octaphenyltetrapyrazinoporphyrazine units. They are soluble in common organic solvents and can be cast int~ strong and flexible films. The maximum absorption wavelength of the poly (aryl ether) s bearing zinc (11) 2,3,9,10,16,17,23,24-octaphenyltetrapyrazinoporphyrazine units in chloroform is 654 nm. 0 1995 John Wiley & Sons, Inc.

Tetrakis(selenodiazole)porphyrazines 1: Tetrakis(selenodiazole)porphyrazine and its Mg(II) and Cu(II) Derivatives. Evidence for their Conversion to Tetrakis(pyrazino)porphyrazines through Octaaminoporphyrazines

“…IR (KBr, cm As was briefly mentioned in the early work by Linstead et al [14], complexes of octaphenyltetrapyrazinoporphyrazine can be prepared by direct template condensation of 2 with the appropriate metal, metal chloride or alcoholate. To our knowledge, however, only complexes of VO [18], Si [19] and Zn [20] have so far been adequately characterized. For the preparation of the magnesium complex, use was made here of the 'propylate method' described above for the solvated TSeDPzMg.…”

Azaphthalocyanines with extended conjugation through heteroaryl and aryl substituents: Photochemical and photophysical properties

“…The synthesis of compounds 5 and 6 (except 5d) has already been published by our group [9] or other groups [10][11][12]22]. In some cases, the published synthetic methods were slightly modified to procedures commonly used in our laboratories.…”

Synthesis and characterization of a novel phthalazinone poly(aryl ether sulfone ketone) with carboxyl group

“…Poly(ether ketone)s (PEK)s and poly(ether sulfone)s (PES)s are the most important high performance engineering thermoplastics, widely used in the electronic, electric, aircraft, and aerospace industries. [1][2][3][4][5][6][7] Initially, considerable effort was made to modify their chemical properties, essentially to improve their thermal properties. 8 In the last few years, more attention has been paid to their functionalization.…”