Today, conventional condition monitoring of installed, operating photovoltaic (PV) modules is mainly based on electrical measurements and performance evaluation. However, such practices exhibit restricted fault-detection ability. This study proposes the use of standard thermal image processing and the Canny edge detection operator as diagnostic tools for module-related faults that lead to hot-spot heating effects. The intended techniques were applied on thermal images of defective PV modules, from several field infrared thermographic measurements conducted during this study. The whole approach provided promising results with the detection of hot-spot formations that were diagnosed to specific defective cells in each inspected module. These evolving hot spots lead to abnormally low performance of the PV modules, a fact that is also validated by the manufacturer's standard electrical tests.