Because of the complicated electronic and metallurgical properties of the metal-semiconductor interface, there is much controversy about the theoretical interpretation of experimental results on Schottky barrier heights. We present a new approach of barrier height measurements on a prototypical clean, abrupt and noninteracting system consisting of mercury contacts to hydrogen-passivated silicon surfaces. The resulting barrier to p-silicon is 0.9 V, totally at variance with all results presented for silicon Schottky barriers fabricated by standard metal deposition techniques. We believe this to be the first report in the limit of noninteracting metal contacts to silicon. PACS numbers: 73.20.-r, 73.30.+y, 73.40.-cThe study of the band lineup between a metal and a semiconductor in intimate contact (Schottky barrier) has led to much controversy concerning the theoretical interpretation of experimental results. Current theoretical models of the band lineup can be divided into two groups. One group of theories proposes that the experimental results are intrinsic to the perfect interface [1]. According to this model the band lineup is determined by the neutrality level at which the Fermi level will normally pin. This opinion currently dominates the physics literature, despite questions as to the universality of the model. The other group of theories postulates an extrinsic effect, typically involving a metallurgical interaction between the metal and the semiconductor, but differing in such details as to the physical origin of this extrinsic effect [2,3]. For example, the two dominant extrinsic models for Schottky barriers both on silicon and on compound semiconductors speculate that the interaction results either in detect formation in the semiconductor material or in an interfacial layer made up of a metallic alloy or mixture of phases. The former model leads to deep levels in the semiconductor, hence changing the band-bending charge distribution within the semiconductor [2], whereas the latter leads to a change in the boundary conditions between the metal and the semiconductor in a simple model of the interface [3].Any experimental attempt to distinguish between intrinsic and extrinsic models of the band lineup must in some fashion modify or eliminate the assumed extrinsic mechanisms. Such mechanisms usually invoke thermally driven or adsorption driven processes. Studies of interface formation at low temperatures have led to the observation of some differences in band alignments [4], but many of these differences are minor and obscured by experimental artifacts such as the photovoltage effects [5] in the photoemission techniques typically used in these studies. Clearly, a different method of investigation is needed on ideal, noninteractive metal-semiconductor interfaces to investigate the band lineup in Schottky barriers.We report here a room-temperature approach which circumvents the possibility of heat of nucleation or adsorption to drive an interaction between the metal and the semiconductor. We achieve this by exp...