Simultaneous Determination of 1-Naphthylacetic Acid and Thiabendazole in Strawberry Tree Berries and Citrus Fruits by Fluorescence Spectrometry

Pulgarı́n, José A. Murillo; Bermejo, Luisa F. García; Rodrı́guez, Sonia

doi:10.1007/s12161-017-1010-3

Cited by 11 publications

(4 citation statements)

References 25 publications

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“…In 2018, Murillo Pulgarín et al [78] presented first-derivative constant wavelength synchronous fluorescence spectrometry as the method for the simultaneous determination of TBZ and 1-naphthylacetic acid in strawberry tree berries and citrus fruit. Although the analytes had overlapped spectra, their simultaneous determination was possible by applying the zero-crossing method to their spectra.…”

Section: Fluorimetrymentioning

confidence: 99%

Review of Characteristics and Analytical Methods for Determination of Thiabendazole

et al. 2023

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Thiabendazole (TBZ) is a fungicide and anthelmintic drug commonly found in food products. Due to its toxicity and potential carcinogenicity, its determination in various samples is important for public health. Different analytical methods can be used to determine the presence and concentration of TBZ in samples. Liquid chromatography (LC) and its subtypes, high-performance liquid chromatography (HPLC) and ultra-high-performance liquid chromatography (UHPLC), are the most commonly used methods for TBZ determination representing 19%, 18%, and 18% of the described methods, respectively. Surface-enhanced Raman spectroscopy (SERS) and fluorimetry are two more methods widely used for TBZ determination, representing 13% and 12% of the described methods, respectively. In this review, a number of methods for TBZ determination are described, but due to their limitations, there is a high potential for the further improvement and development of each method in order to obtain a simple, precise, and accurate method that can be used for routine analysis.

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Section: Fluorimetrymentioning

confidence: 99%

Review of Characteristics and Analytical Methods for Determination of Thiabendazole

et al. 2023

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“…Synchronous fluorescence spectrometry, a technique initially described by Lloyd [16] in 1971 to map fluorescence spectra in the presence of simultaneous scanning of both excitation and emission monochromators, has been widely utilized for the investigation of mixtures. The simultaneous fluorescence approach is used by a growing number of scientists for the determination of compounds in complicated matrices, and it may be combined with other techniques, such as derivative technique, to accomplish further spectral separations [17][18][19][20][21][22]. Among these, the constant-energy synchronous fluorescence approach utilized in this work can effectively simplify the spectra, narrow the spectral band, and eliminate the influence of scattered light by selecting an appropriate constant-energy difference, making it advantageous for the detection of mixtures.…”

Section: Introductionmentioning

confidence: 99%

Machine Learning-Assisted Synchronous Fluorescence Sensing Approach for Rapid and Simultaneous Quantification of Thiabendazole and Fuberidazole in Red Wine

Wei

Chen

et al. 2022

Sensors

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Rapid analysis of components in complex matrices has always been a major challenge in constructing sensing methods, especially concerning time and cost. The detection of pesticide residues is an important task in food safety monitoring, which needs efficient methods. Here, we constructed a machine learning-assisted synchronous fluorescence sensing approach for the rapid and simultaneous quantitative detection of two important benzimidazole pesticides, thiabendazole (TBZ) and fuberidazole (FBZ), in red wine. First, fluorescence spectra data were collected using a second derivative constant-energy synchronous fluorescence sensor. Next, we established a prediction model through the machine learning approach. With this approach, the recovery rate of TBZ and FBZ detection of pesticide residues in red wine was 101% ± 5% and 101% ± 15%, respectively, without resorting complicated pretreatment procedures. This work provides a new way for the combination of machine learning and fluorescence techniques to solve the complexity in multi-component analysis in practical applications.

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“…Thiabendazole (TBZ, C 10 H 7 N 3 S, CAS registry number: 148-79-8, Figure ), 4-(1 H -1,3-benzimidazol-2-yl)-1,3-thiazole, is an important compound derived from benzimidazole and thiazole. It has been applied in several domains, such as medicine and pharmaceutical sciences, agriculture, and food industry. , As a broad spectrum of anthelmintic, it is rapidly absorbed upon ingestion and used in the treatment of many types of roundworm infections, such as threadworm, hookworm, and large roundworm. In agriculture, it is used as an antifungal agent and food additive to keep fresh of fruits. , Also, TBZ is reported as an organic chemical compound, which has the potential of treating some types of cancer …”

Section: Introductionmentioning

confidence: 99%

“…It has been applied in several domains, such as medicine and pharmaceutical sciences, agriculture, and food industry. 1,2 As a broad spectrum of anthelmintic, it is rapidly absorbed upon ingestion and used in the treatment of many types of roundworm infections, such as threadworm, hookworm, and large roundworm. In agriculture, it is used as an antifungal agent and food additive to keep fresh of fruits.…”

Section: Introductionmentioning

confidence: 99%

Solubility Measurement and Data Correlation of Thiabendazole in 12 Pure Organic Solvents from 283.15 to 323.15 K

Ouyang

Wang

et al. 2020

J. Chem. Eng. Data

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The solubility of thiabendazole (TBZ) in 12 organic solvents (methanol, ethanol, n-propanol, isopropanol, nbutanol, isobutanol, acetone, butanone, methyl acetate, ethyl acetate, n-butyl acetate, and acetonitrile) was determined by the gravimetric method from 283.15 to 323.15 K. The solubility in all selected solvents increases with increasing temperature and in acetonitrile changes much greater than that in other solvents as temperature increases. The solubility of TBZ is higher in alcohol and ketone solvents than those in esters and nitriles. Besides, the solubility is mainly related to the solvent polarity and cohesive energy density in nonalcohols and influenced by the complicated combination of many factors in alcohols. Further, the Apelblat model, λh model, and NRTL model were used to correlate the solubility of TBZ. The relative deviation is less than 2.23% with the modified Apelblat equation, which shows better fitting performance compared with other two models.

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Simultaneous Determination of 1-Naphthylacetic Acid and Thiabendazole in Strawberry Tree Berries and Citrus Fruits by Fluorescence Spectrometry

Cited by 11 publications

References 25 publications

Review of Characteristics and Analytical Methods for Determination of Thiabendazole

Review of Characteristics and Analytical Methods for Determination of Thiabendazole

Machine Learning-Assisted Synchronous Fluorescence Sensing Approach for Rapid and Simultaneous Quantification of Thiabendazole and Fuberidazole in Red Wine

Solubility Measurement and Data Correlation of Thiabendazole in 12 Pure Organic Solvents from 283.15 to 323.15 K

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