Solubility of Carbon Dioxide in Acetone and Propionic Acid at Temperatures between 298 K and 333 K

Abstract

The solubility of carbon dioxide in organic solvents acetone and propionic acid has been measured with an analytical method. The composition and the density of the liquid phase in the binary vapor−liquid equilibrium have been investigated at (313 and 333) K (for the system carbon dioxide + acetone) and at (298, 313, and 333) K (for the system carbon dioxide + propionic acid) at pressures up the binary critical pressure. The experimental results for the phase equilibrium have been correlated with the Peng−Robinson EOS applying several mixing rules.

High-pressure (vapour + liquid) equilibria in (carbon dioxide+ acetone or 2-propanol) at temperatures from 293 K to 333 K

“…Table 6 gives a summary of the data sources. As the experimental data were not reported at the temperatures covered in the present equilibrium literature data for T = 323 K ( , Xu et al (35) ) and T = 333 K (•, Traub and Stephan, (34) , Adrian and Maurer (30) ) and with calculations (-, Peng-Robinson equation of state). work, the comparison with literature data is done by using the equations of state.…”

“…Both calculation procedures give very similar results. Figure 4 shows a detailed comparison with the data of Xu et al (35) (for T = 323 K) and those of Adrian and Maurer (30) and of Traub and Stephan (34) (for T = 333 K) for (carbon dioxide + acetone). The results of these references agree with the new experimental data to nearly within the experimental uncertainty.…”

Carboxylation of Arene CH Bonds with CO2: A DFT‐Based Approach to Catalyst Design

“…[38] These concentrations, as well as a temperature of 80 8C, are the conditions used within the energetic span model to calculate the TOFs reported herein.…”

Drying processes for preparation of titania aerogel using supercritical carbon dioxide

“…Phase diagram for CO 2 + acetone system: SC-1 ( ), SC-2 ( ), SC-3 ( ), SC-4 ( ), critical point of CO 2 (♦), critical locus for CO 2 + acetone system (-) byAdrian and Maurer (1997), vapor pressures of CO 2 (---) bySpan and Wagner (1996).supply part, a drying cell[9], an on-line FT-IR spectrometer [10] and a solvent trap part[13]. The drying cell was immersed in a water bath[16] and controlled in the focused temperature within ±0.1 K. The pressures in the system were maintained within ±0.12 MPa during the drying.…”