Synchrotron‐based microprobe investigation of impurities in raw quartz‐bearing and carbon‐bearing feedstock materials for photovoltaic applications

Abstract

Using synchrotron‐based analytical microprobe techniques, we determine micrometer‐scale elemental composition, spatial distribution, and oxidation state of impurities in raw feedstock materials used in the photovoltaic industry. Investigated Si‐bearing compounds are pegmatitic quartz, hydrothermal quartz, and quartzite. Micrometer‐scale clusters containing Fe, Ti, and/or Ca are frequently observed at structural defects in oxidized states and in bulk concentrations equivalent to inductively coupled plasma mass spectroscopy measurements. Investigated C‐bearing compounds are pine wood, pine charcoal, and eucalyptus charcoal. Clustered metals are observed only in the charcoal samples. Impurity clustering implies that industrial processing could be adapted to take advantage of this “natural gettering” phenomenon, expanding the usable range of raw feedstock materials to dirtier, cheaper, and more abundant ones, currently underexploited for solar‐grade silicon production. Copyright © 2011 John Wiley & Sons, Ltd.

2013 Atomic spectrometry update—A review of advances in X-ray fluorescence spectrometry

“…Interesting results using m-SRXRF spectrometry in the analysis of impurities in raw quartz-bearing and carbon-bearing feedstock materials for photovoltaic applications were found by Bernardis et al 46 These investigations of the silicon-bearing compounds, pegmatitic quartz, hydrothermal quartz and quartzite, showed micro-scale clusters containing oxidised states of Fe, Ti and/or Ca at structural defects. The authors also found that in three carbon-bearing samples, pine wood, pine charcoal and eucalyptus charcoal, clustered metals were only observed in the charcoal samples.…”