The influence of time reaction to characteristic of methyl ester sulfonate from seed oil ketapang

Abstract

Methyl Ester Sulfonate had been prepared From Ketapang Seed Oil and was used as Surfactant. The optimum condition obtained by conducting preparation in various reaction time (3.5; 4.0; 4.5; 5.0; 5.5 hours). The methyl ester was analysis by GC-MS and sulfonate group was identified by using FTIR spectroscopy. GC-MS result showed the ester consisted of methyl palmitoleic, methyl linoleic, methyl palmitate, methyl stearate, methyl oleic, methyl palmitolenat and methyl eicosenoate. The optimum condition of methyl ester sulfonate achieved at reaction time 4.5 hours provided mass of methyl ester sulfonate obtained 34.85 g. FTIR spectra of sulfonate group indicated by shifting of wave number at 1118.71cm-1 to 1029.1 cm-1. The methyl ester sulfonate has emulsion stability 71.684%, density 0.8714 g/mL, surface tension 36.232 dyne/cm 2 , and maximum absorbance 1.428 at 660 nm wavelength.

Influence of process conditions on the sulfonation of methyl ester synthesized from used cooking oil: Optimization by Taguchi approach

“…It was discovered that the MES from this study has slightly higher absorbance than commercial surfactant. It is also worth noting that the absorbance of the MES produced herein was 1.54 at 640 nm wavelength which can be compared to value of absorbance (1.51) reported for MES produced by Chemiton Corporation of United States (Hariani et al, 2016).…”

“…The absorbances of self-synthesized and commercially produced MES were calculated using the method described by Jurado et al (2006). To determine this parameter, a UV-vis scanning spectrophotometer (Jenway 6715) was used to evaluate anionic surface active agents on methylene blue in tap water samples (Hariani et al, 2016). The maximum absorbances of the two samples were measured at wavelengths ranging from 500 to 700 nm.…”

“…Temperature, time, sulfonating agent to ME molar ratio and aging conditions are all operating variables that affect the sulfonation reaction. These process parameters, particularly the sulfonating agent/ME molar ratio, have a significant impact on sulfonation product yields (Foster, 1997; Hariani et al, 2016; Xie et al, 2013). Although few studies on the influence of factors affecting the sulfonation process have been conducted using one factor at a time (OFAAT) method (Permdani et al, 2018; Xie et al, 2013), the evaluation of the influence of operational parameters using experimental design technique has not been reported.…”

Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk

“…Penelitian terdahulu yang dilakukan oleh Rachmawati [2] menunjukkan kondisi operasi optimum reaksi sulfonasi dapat dicapai pada rasio mol biodiesel minyak kelapa sawit terhadap natrium bisulfit sebesar 1:2,169 pada suhu reaksi 105°C dengan waktu reaksi 4 jam. Sedangkan Hariani [5] mendapatkan hasil optimum pada suhu reaksi 100°C dan waktu reaksi 4,5 jam menggunakan metil ester yang diperoleh dari biji ketapang dan disulfonasi dengan NaHSO3 pada perbandingan mol 1:1,5. Penelitian kami bertujuan untuk mempelajari pengaruh rasio mol reaktan pada tahap metanolisis, waktu dan suhu reaksi terhadap yield MES.…”