2012
DOI: 10.1016/j.jaap.2012.08.003
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Thermal stability of fatty acids in subcritical water

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Cited by 46 publications
(20 citation statements)
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“…The active substances produced by PN appear to be heatstable up to 120°C. Furthermore, linoleic acid, a major fraction of chlorellin, as well as other FAs, were found to be stable at a temperature of 300°C or below (Shin et al 2012).…”
Section: Discussionmentioning
confidence: 99%
“…The active substances produced by PN appear to be heatstable up to 120°C. Furthermore, linoleic acid, a major fraction of chlorellin, as well as other FAs, were found to be stable at a temperature of 300°C or below (Shin et al 2012).…”
Section: Discussionmentioning
confidence: 99%
“…To minimize thermal degradation of biodiesel, Imahara et al [4] suggested that the supercritical methanol method should be carried out at temperature below 300 8C, preferably at 270 8C, with a pressure higher than 8.09 MPa. Shin et al [5] reported that degradation of unsaturated fatty acids, found in vegetable oils in the presence of water, was observed at temperatures above 250 8C with an operating pressure of 20 MPa. Different co-solvents, propane [6], heptane [7] and carbon dioxide [8] have been used to lower temperature to 280 8C in the supercritical methanol method.…”
Section: Introductionmentioning
confidence: 99%
“…As previously, the figure of soybean and jatropha oils are not shown as they are relatively similar to sunflower oil and palm oil respectively. shown in previous studies [19,26]. Fujii et al [27] demonstrated that fatty acids commonly only start to degrade above 300 °C.…”
Section: Effect Of Htl Temperature On Oil Compositionmentioning
confidence: 78%
“…The type of isomer present also effects the direction of the reaction, for instance the breakdown of the cis-form of oleic acid produces undecene and the trans-form produces heptanoic acid [26]. Mono substituted aromatic compounds are also formed by endocyclization and di-substituted aromatics can also be formed by exo-cyclization such as 1-ethyl-2-methyl-benzene which is formed by the cyclization of nonene [34,35].…”
Section: Discussionmentioning
confidence: 99%