Thisthesis reports a studyof themechanism ofelectromigration failure inAI-2Cu-1Si thin-film conducting lines on Si. Sampleswcrc patterned from0.5_m thick vapor-deposited films withvarious mean grain sizes (G), and had lines widths (W) of 1.3, 2,4 and 6 _m, providing aneffective linewidth (W/G) rangeofapproximately from0.5to3. The lines wereagedatvarious conditions tochangetheCu-precipitatc distribution and were then tested to failure at T = 225°C and j = 215x106 A/cm 2. Some samples were tested over a range of substrate temperatures, current densities and current reversal times. Aging produces an initially dense distribution of metastable 0' (A12Cu; coherent) in the grain interiors, with stable 0 (A12Cu; incoherent) at the grain boundaries. The intragranular 0' is gradually absorbed into the grain boundary precipitates, lowering the density of intragranular precipitates. In the wide lines (W/G > 1) the mean time to failure increases slowly and monotonically with pre-aging time and current reversal time. The failure mode is the formation and coalescence of voids that form on grain boundaries with an appa.rent activation energy of 0.65 eV. In the narrow lines (W/G < 1), the lines failed by a transgranular-slit mechanism with an activation energy near 0.93 eV, in which voids forms in the bamboo grains that terminate the longest polygranular segments in the line t i, due to accumulation of a supersaturation of vacancies. The distribution of the polygranular segments and the kinetics of failure varies with the linewidths, which provides an explanation for the dependence of failure statistics on line geometry. Failure occurs after Cu has been swept from the grains that fail. Pre-aging the line to create a more stable i distribution of Cu lengthens the time required to sweep Cu from the longest polygranular segment, and significantly increases the time to failure. In the optimum case when the density of intragranular O-phase precipitates is maximized, the transgranular-slit failure mechanism is suppressed, and the bamboo grain fails by diffuse thinning to rupture. The results from the current reversal test indicate that the time to sweep Cu in the polygranular segments is longer for longer polygranular segments, and have the consequence that the time to first failure in an array of lines is much longer than predicted by a log-normal fit to the distribution of failure times.