%675$&7We report on optical transmission properties and results of optical waveguide characterization of flourinated hyperbranched polymers and dendrimers (details on chemical synthesis were reported recently [1]). The polymers and dendrimers allow the introduction of additional functionality, such as cross-linking and refractive index tuneability. The dendrimers having a similar bulk structure as the hyperbranched polymer were also shown to house lanthanide cations for optical amplifying application. The fluorinated bulk structure results in a low contribution from vibration overtones in the absorption spectra in the NIR/IR region (800 -2200 nm). The refractive index of the fundamental fluorinated hyperbranched polymer was found to be tuneable between ca 1.45 and 1.65 by incorporating various substituents. Optical losses were measured to be below ca 0.5 dB/cm at 1550 nm.Keywords: fluorinated polymer waveguide, hyperbranched polymer, dendrimer, lanthanide cation, optical waveguide ,1752'8&7,21Polymer based materials provide synthetic and processing options that are not available with traditional photonic materials based on glasses, insulators and semiconductors. In addition to excellent optical functionality the good mechanical properties along with environmental compatibility can make polymers a cost-effective alternative. During the past decade, this has motivated the search for high-performance polymers that would enable easier fabrication at low cost in larger integrated systems [2][3][4]. Dendritic macromolecules are highly-branched structures synthesized from AB x -type monomers (where x is two or greater) resulting in a multitude of end-groups that can be used to attach various functional groups. Modifications of the number and type of end-group functionality on dendritic polymers are essential in order to control their solubility, adhesion to various surfaces, self-assembly, chemical recognition, as well as their electronic, electrochemical, optical and luminescence properties. Such modifications have led to abundant potential applications [5], and also mixtures of end-groups are possible to obtain. This allows tailoring of multi-functional photonic materials and this has encouraged us to develop certain fluorinated hyperbranched and dendritic polymer systems [1,6,7] for use at telecommunication wavelengths. Thus, the materials should be highly transparent in the near infrared (NIR), especially at 1310 and 1550 nm. In the NIR, polymer materials exhibit high absorption or high optical losses compared to silica fibers. This drawback can be limited by shifting the high-absorption signal toward longer wavelengths, by replacing hydrogen atoms with heavier atoms such as halogens, especially chlorine, fluorine or deuterium [8]. In addition to low optical loss and control of refractive index, such materials should have good thermal stability (over 200 ºC), good mechanical properties and ease in processing.Metal ions can be incorporated in order to obtain a suitable light amplification function. In laser and optic...