We present the results of an experimental study of patterned segregation in a horizontally shaken shallow layer of a binary mixture of dry particles. An order parameter for the segregated structures is defined and the effect of the variation of the combined filling fraction, C, of the mixture on the observed pattern formation is systematically studied. The surprising result is that there is a critical event associated with the onset of the pattern, at C = 0.647 ± 0.049, which has the characteristics of a second order phase transition, including critical slowing down.PACS numbers: 01.50Pa, 45.70Mg, 64.75.+g, 68.35.Rh, 45.70Qj. Keywords: Experiment, granular, binary mixture, segregation, critical phenomena, pattern formation.Segregation is a counter-intuitive phenomenon where an initially mixed state of dry granular particles separates into its constituent components under excitation [1]. Intriguingly, it does not always happen and the conditions for its occurrence are difficult to predict. Segregation is not only of fundamental interest but it is also of practical importance with applications in areas ranging from industry[2] to geology [3]. In recent years, there has been an upsurge of interest in small scale laboratory studies where vibration [4,5], avalanching in partially filled horizontal rotating drums [6,7] and stratification in vertically poured mixtures [8] have all provided interesting examples of pattern formation.Our focus is on quasi-2-dimensional horizontally driven layers of binary mixtures of particles [9,10] as this gives the practical advantage that any collective behavior is readily visualized and gravity is effectively eliminated. Moreover, the material is in contact with the drive throughout the motion. For this class of binary granular systems a qualitative segregation mechanism has been suggested [11] borrowing the idea of excluded volume depletion from colloidal systems and binary alloys [12]. In a driven 2D binary system of particles of different sizes, the packing fraction of the system is decreased if self-organized clustering of the larger particles occurs. Thereby considerably increasing the number of configurational states of the system. Hence ordered arrangement of the large spheres can increase the total entropy of the system by increasing the mobility of the small particles. This process has been referred to as entropic ordering [1]. We believe that analogous attractive depletion forces are responsible for segregation in our granular system. We show that segregation undergoes a phase transition and occurs only for filling fractions above a critical value with the characteristics of a second order phase transition with critical slowing down.A schematic diagram of the top view of the apparatus is presented in Fig. 1. It consisted of a horizontal smooth rectangular tray, of dimensions (x, y) = 180×90mm with a flatness of less than ±5µm, on which a binary mixture of particles was vibrated longitudinally. The tray, made out of aluminum tool plate, was mounted on a system of four high p...