2020
DOI: 10.3390/electrochem1010002
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Ultrathin Film PtxPd(1-x) Alloy Catalysts for Formic Acid Oxidation Synthesized by Surface Limited Redox Replacement of Underpotentially Deposited H Monolayer

Abstract: This work emphasizes the development of a green synthetic approach for growing ultrathin film PtxPd(1-x) alloy catalysts for formic acid oxidation (FAO) by surface limited redox replacement of underpotentially deposited H sacrificial layer. Up to three-monolayers-thick PtxPd(1-x) films with different composition are generated on Au electrodes and characterized for composition and surface roughness using XPS and electrochemical methods, respectively. XPS results show close correlation between solution molar rat… Show more

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Cited by 3 publications
(1 citation statement)
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References 114 publications
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“…Guo et al synthesized Te nanowires via the hydrothermal method, then synthesized Pd nanowires with Te nanochains as a reducing agent and template and, finally, synthesized PtPd nanowires using ascorbic acid as a reducing agent precursor. Achari I. prepared an ultra-thin Pt x Pd (1−x) alloy catalyst by the low potential deposition of a H sacrificial layer surface, restricting redox replacement [25]. However, the reaction time required by the above-synthesized methods is relatively long and the reaction process is very complicated.…”
Section: Introductionmentioning
confidence: 99%
“…Guo et al synthesized Te nanowires via the hydrothermal method, then synthesized Pd nanowires with Te nanochains as a reducing agent and template and, finally, synthesized PtPd nanowires using ascorbic acid as a reducing agent precursor. Achari I. prepared an ultra-thin Pt x Pd (1−x) alloy catalyst by the low potential deposition of a H sacrificial layer surface, restricting redox replacement [25]. However, the reaction time required by the above-synthesized methods is relatively long and the reaction process is very complicated.…”
Section: Introductionmentioning
confidence: 99%