Polyaniline nanofibres can be prepared by a number of methods based on chemical oxidative polymerization and in situ adsorption polymerization. However, the lack of alignment in these nanostructures makes them unsuitable for many applications. Here, we report a simple approach to chemical oxidative polymerization that can control the growth and simultaneous alignment of polyaniline nanofibres grown on a range of conducting and non-conducting substrates in a wide variety of sizes. The diameters of the tips of the nanofibres can be controlled within the range 10-40 nm, and the average length can be controlled within the range 70-360 nm. Moreover, the coatings display a range of properties including superhydrophilicity and superhydrophobicity. Such nanostructured coatings may be useful for applications such as anti-fog coatings, self-cleaning surfaces, DNA manipulation, transparent electrodes for low-voltage electronics, and chemical and biological sensors.
Contrary to the image of college campuses as “ivory towers,” the victimization of college students recently has been portrayed as a serious problem deserving policy intervention. Based on interviews designed after the National Crime Victimization Survey, which were conducted with 3,472 randomly selected students across 12 institutions, we examined both the level and sources of students'victimization. More than one‐third of the sample reported being victims during the 1993–94 academic year. Informed by the lifestyle‐routine activities approach, the analysis revealed that the risk of property victimization was increased by proximity to crime, target attractiveness, exposure, and lack of guardianship. The main predictor of violent victimization was a lifestyle that included high levels of partying on campus at night and the recreational use of drugs.
Simulations of solar radiation have become increasingly common in recent years because of the rapid global development and deployment of solar energy technologies. The effect of air pollution on solar radiation is well known. However, few studies have attempting to evaluate the potential of the air pollution index in estimating solar radiation. In this study, meteorological data, solar radiation, and air pollution index data from three sites having different air pollution index conditions are used to develop random forest models. We propose different random forest models with and without considering air pollution index data, and then compare their respective performance with that of empirical methodologies. In addition, a variable importance approach based on random forest is applied in order to assess input variables. The results show that the performance of random forest models with air pollution index data is better than that of the empirical methodologies, generating 9.1-17.0% lower values of root-mean-square error in a fitted period and 2.0-17.4% lower values of root-mean-square error in a predicted period. Both the comparative results of different random forest models and variance importance indicate that applying air pollution index data is improves estimation of solar radiation. Also, although the air pollution index values varied largely from season to season, the random forest models appear more robust performances in different seasons than different models. The findings can act as a guide in selecting used variables to estimate daily solar radiation and improve the accuracy of solar radiation estimation.
Two major concerns in the design and fabrication of microfluidic biochips are protein binding on the channel surface and protein denaturing during device assembly. In this paper, we describe new methods to solve these problems. A "fishbone" microvalve design based on the concept of superhydrophobicity was developed to replace the capillary valve in applications where the chip surface requires protein blocking to prevent nonspecific binding. Our experimental results show that the valve functions well in a CD-like ELISA device. The packaging of biochips containing pre-loaded proteins is also a challenging task since conventional sealing methods often require the use of high temperatures, electric voltages, or organic solvents that are detrimental to the protein activity. Using CO2 gas to enhance the diffusion of polymer molecules near the device surface can result in good bonding at low temperatures and low pressure. This bonding method has little influence on the activity of the pre-loaded proteins after bonding.
In this paper, we describe an interstitial bonding technique for packaging of microfluidic chips. The cover plate is first placed on top of the microfluidic chip, followed by dispensing the UV-curable resin into the resin-loading reservoirs. With the interstitial space between the cover plate and the microfluidic chip connecting to the loading reservoirs, the UV-curable resin wicks through capillary force action and hydrostatic pressure generated by the liquid level in the resin-loading reservoirs. When reaching the microchannels, the UV-curable resin stops flowing into the microchannels due to the force balance between the surface tension and hydrostatic pressure. The assembly is then placed under the UV light, followed by further curing in the thermal oven. It is found that there is no leakage from the bonded microfluidic chips and a good DNA separation result was obtained by using the microfluidic chips as fabricated. This bonding technique is relatively simple and fast, which can be applied to the packaging of microfluidic chips made from hybrid materials with complicated designs as long as the interstitial space connects to the loading reservoirs.
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