We report the first observation of the parity-violating gamma-ray asymmetry A np γ in neutronproton capture using polarized cold neutrons incident on a liquid parahydrogen target at the Spallation Neutron Source at Oak Ridge National Laboratory. A np γ isolates the ∆I = 1, 3 S1 → 3 P1 component of the weak nucleon-nucleon interaction, which is dominated by pion exchange and can be directly related to a single coupling constant in either the DDH meson exchange model or pionless effective field theory. We measured A np γ = (−3.0 ± 1.4(stat.) ± 0.2(sys.)) × 10 −8 , which implies a DDH weak πN N coupling of h 1 π = (2.6 ± 1.2(stat.) ± 0.2(sys.)) × 10 −7 and a pionless EFT constant of C 3 S 1 → 3 P 1 /C0 = (−7.4 ± 3.5(stat.) ± 0.5(sys.)) × 10 −11 MeV −1 . We describe the experiment, data analysis, systematic uncertainties, and implications of the result.

The thermogenic transformation of kerogen into hydrocarbons accompanies the development of a pore network within the kerogen that serves as gas storage locations both in pore space and the surface area for adsorbed gas with source rocks. Therefore, the successful recovery of gas from these rocks depends on the accessible surface area, surface properties, and interconnectivity of the pore system. These parameters can be difficult to determine because of the nanoscale of the structures within source rocks. This study seeks to investigate the pore structure, surface heterogeneity, and composition of isolated kerogens with progressively increasing thermogenic maturities from source rocks at a middle-east reservoir. Prompt gamma-ray activation analysis (PGAA), nitrogen and methane volumetric gas sorption, and small-angle neutron scattering (SANS) are combined to explore the relationship between the chemical composition, pore structure, surface roughness, surface heterogeneity, and maturity. PGAA results indicate that more mature kerogens have lower hydrogen/carbon ratios. Nitrogen gas adsorption indicates that the pore volume and accessible specific surface area are higher for more mature kerogens. The methane isosteric heat at different methane uptakes in the kerogens is determined by methane isotherms and shows that approximately two types of binding sites are present in less mature kerogens while the binding sites are relatively homogeneous in the most mature kerogen. The hysteresis effects of the structure during the adsorption and desorption processes at different CD 4 gas pressures are studied. An extended generalized Porod's scattering law method (GPSLM) is further developed here to analyze kerogens with fractal surfaces. This extended GPSLM quantifies the surface heterogeneity of the kerogens with a fractal surface and shows that more mature kerogen is chemically more homogeneous, consistent with the results from methane isosteric heat. SANS analysis also suggests a pronounced surface roughness in the more mature kerogens. A microporous region circling around the nanopores, which contributes to high surface roughness and methane storage, is shown to develop with maturity.

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The accuracy of low-level hydrogen measurements with prompt gamma-ray activation analysis (PGAA) depends on identifying and accounting for all background H signals, including interfering signals. At the cold-neutron (CN)PGAA facility at the NIST Center for Neutron Research, the sources of background H signals were investigated in the context of titanium-based matrices containing low-levels of H (<300 mg H per kg Ti) with the measurements of prepared standards (mixtures of polyvinyl chloride and titanium oxide) and Ti alloy (Ti6Al4V) samples. The sensitivity ratio, defined as the ratio of the H signal to the Ti signal per unit mass ratio of H in Ti, was determined (1) with the measurements of prepared standards and (2) based on partial gamma-ray production cross sections and full-energy detection efficiencies. The resulting calibrations from these two approaches agreed within experimental uncertainty. A series of Ti alloy NIST Standard Reference Materials (SRMs) previously certified for the H content (SRMs 2452, 2453, 2453a, 2454) were used as test cases, with the mass fractions determined based on the sensitivity ratios derived from method 1 and method 2, respectively. The results agreed with the certified values within experimental uncertainties, validating the analysis performed on the new instrument with newly-prepared standards at low H mass fractions (method 1), and with the standard-independent analysis (method 2). Various sample mounting improvements were made to lower the background H signal. Spectral interferences near the H peak were identified as potential sources of bias and as a limiting factor in the detection limit of H in Ti alloy samples.