UV-Vis spectroscopy is a versatile analytical tool used to examine the nature of various synthetic, biological and clinical molecules for pharmaceutical and environmental applications. The analysis is typically performed in...
Blood group analysis has evolved from conventional “test-tube” to ingenious “lab-on-a-chip” micro/paper-fluidic devices for identifying blood phenotypes. Despite rapid and economical, fabrication of these devices require Whatman paper that is...
Metal nanoparticles grafted within inert and porous wide-area
supports
are emerging as recyclable, sustainable catalysts for modern industry
applications. Here, we bioengineered gold nanoparticle-based supported
catalysts by utilizing the innate metal binding and reductive potential
of eggshell as a sustainable strategy. Variable hand-recyclable wide-area
three-dimensional catalysts between ∼80 ± 7 and 0.5 ±
0.1 cm2 are generated simply by controlling the size of
the support. The catalyst possessed high-temperature stability (300
°C) and compatibility toward polar and nonpolar solvents, electrolytes,
acids, and bases facilitating ultra-efficient catalysis of accordingly
suspended substrates. Validation was done by large-volume (2.8 liters)
dye detoxification, gram-scale hydrogenation of nitroarene, and the
synthesis of propargylamine. Moreover, persistent recyclability, monitoring
of reaction kinetics, and product intermediates are possible due to
physical retrievability and interchangeability of the catalyst. Finally,
the bionature of the support permits ∼76.9 ± 8% recovery
of noble gold simply by immersing in a royal solution. Our naturally
created, low-cost, scalable, hand-recyclable, and resilient supported
mega-catalyst dwarfs most challenges for large-scale metal-based heterogeneous
catalysis.
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