Increasing research activity on cellulose nanofibril-based materials provides great opportunities for novel, scalable manufacturing approaches. Cellulose nanofibrils (CNFs) are typically processed as aqueous suspensions because of their hydrophilic nature. One of the major manufacturing challenges is to obtain dry CNFs while maintaining their nano-scale dimensions. Four methods were examined to dry cellulose nanocrystal and nanofibrillated cellulose suspensions: (1) oven drying, (2) freeze drying (FD), (3) supercritical drying (SCD), and (4) spray-drying (SD). The particle size and morphology of the CNFs were determined via dynamic light scattering, transmission electron microscopy, scanning electron microscopy, and morphological analysis. SCD preserved the nano-scale dimensions of the cellulose nanofibrils. FD formed ribbon-like structures of the CNFs with nano-scale thicknesses. Width and length were observed in tens to hundreds of microns. SD formed particles with a size distribution ranging from nanometer to several microns. Spray-drying is proposed as a technically suitable manufacturing process to dry CNF suspensions.
Applications
of cellulose nanomaterials (CNMs) have attracted increasing
attention in recent years. One conceivable path lies in their commercial
applications for packaging, in which their barrier properties will
play an important role in determining their competiveness with conventional
materials. This review critically analyzes the performance of CNMs
acting as a barrier against moisture and oxygen permeation in CNM
films, CNM-coated polymers and papers, and CNM-reinforced polymer
composites, gives some insights into remaining challenges, and brings
an overall perspective of compositing CNMs with other materials to
achieve balanced properties adequate for barrier packaging. In general,
CNMs are a poor moisture barrier but excellent oxygen barrier in the
dry state and are still good below 65% relative humidity. The addition
of CNMs can improve the oxygen barrier of the resulting polymer composites;
however, neat CNM coatings and films can afford better oxygen barrier
properties than dispersed CNMs in coatings and nanocomposites. The
morphology and surface functionality of CNMs can be tailored to maximize
the barrier performance of materials comprising them. The higher the
surface charge density is of CNMs, the better is the barrier performance
of coated polymers. Like other oxygen barriers such as ethylene vinyl
alcohol and cellophane, the moisture sensitivity and sealability of
CNMs can be improved by sandwiching them with high moisture-resistant
and sealable polymers such as a polyolefin. A multilayered structure
with layers of CNMs providing oxygen resistance covered by other layers
of polymers providing moisture resistance and sealability might be
competitive in barrier packaging markets dominated by synthetic plastics.
This paper provides a review of the scientific literature concerned with adhesion and surface properties of cellulose and nanocellulose. Cellulose is the most abundant chemical compound on earth and its natural affinity for self-adhesion has long been recognized. The ease of adhesion that occurs in cellulose has contributed to its use in paper and other fiber-based composite materials. Cellulose adhesion, which has received considerable attention over the past half century, occurs over a practical length scale ranging from the nanoscale to millimeters. Adhesion theories that have been examined in the bonding of cellulose fibers include: mechanical interlocking, adsorption or wetting theory, diffusion theory, and the theory of weak boundary layers. Cellulose fibers on the nanoscale are prepared in four different ways: (1) bacterial cellulose nanofibers, (2) cellulose nanofibers by electrospinning, (3) microfibrillated cellulose plant cell fibers and (4) nanorods or cellulose whiskers. Structure and properties of nanocellulose that are important include: morphology, crystalline structure, surface properties, chemical and physical properties, and properties in liquid suspension. Cellulosic nanofibers present a very high surface area which makes the adhesion properties the most important parameter to control for nanocomposite applications. In this paper, we will focus on discussion of the adhesion and surface characteristics of cellulose nanofibers that impact its properties and application in nanomaterials. Koninklijke Brill NV, Leiden, 2008
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