A p-type semiconductor CuO film with a bandgap energy of 1.4 eV has been prepared by anodic electrodeposition in a basic aqueous solution containing copper nitrate hydrate and ammonium nitrate at 297 K, and the structural, optical, and electrical characterizations were carried out. The randomly-oriented CuO film prepared on a transparent conductive glass substrate showed electrical characteristics of a 1.26 × 103 Ω cm in resistivity, 2.11 × 1016 cm−3 in carrier concentration, and 0.234 cm2 V−1 s−1 in mobility, and a slight photocurrent generation could be observed during light irradiation. The (002)-oriented CuO film could be prepared on the (111)-oriented Au/Si wafer substrate and possessed an excellent photoactivity of a large photocurrent density and quick response compared to those for the randomly oriented CuO film.
Cl-doped ZnO-nanowire (Cl:ZnO-nws)/Cu2O photovoltaic devices were prepared by electrodeposition in aqueous solutions, and the effects of the insertion of the highly resistive ZnO (i-ZnO) layer has been demonstrated by an improvement of the photovoltaic performance. The Cl:ZnO-nws and i-ZnO layer were prepared by electrodeposition in a zinc chloride aqueous solution with saturated molecular oxygen and simple zinc nitrate aqueous solution, respectively. The i-ZnO layer was directly deposited on the Cl:ZnO-nws and suppressed the electrodeposition of the Cu2O layer on the Cl:ZnO-nws. The insertion of the i-ZnO layer between the Cl:ZnO-nws and Cu2O layers induced an improvement in the photovoltaic performance from 0.40 to 1.26% with a 0.35 V open circuit voltage, 7.1 mA·cm(-2) short circuit current density, and 0.52 fill factor due to the reduction of the recombination loss.
In the last years, there is an increasing acknowledgment of our impact on the environment due to our lifestyle, while the need to adopt a more sustainable approach as to our consumption habits emerges as of particular significance. This trend regards industrial sectors affecting the consumption habits and, especially, electronic industry where the short life cycles and the rapidly developing technology have led to increased e-waste volumes, such as discarded electronic equipment. Waste Electric and Electronic Product or E-waste is referred to all kind of electric and electronic equipments and appliances that is thrown by users. The majority of such elements result in landfills because it is inexpensive disposal option. The E-waste has become a matter of concern because of toxic and hazardous present in electronic goods and if not properly managed. This equipments are a complicated assembly of thousand material, many of which one highly toxic such as brominates substances, toxic gases, toxic metals, biologically active material, acids, plastics and plastics additives. However, their partial recyclability, due to their material composition along with the unavoidable restrictions in landfills, has led to the development of retrieval techniques for their recycling and re-use, highlighting the significance of e-waste recycling, not only from a waste management aspect but also from a valuable materials' retrieval aspect. This paper provides an overview of E-waste generation and management in Malaysia, which, with rapid economic growth and urbanization, is becoming a major social and environmental issue. Thus, major concern for E-waste management in Malaysia has addressed to environmental protection, compared to quantity control. The challenge now is to make the practice effectively in the many different contexts in Malaysia.
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