The 39-day long eruption at the summit of Eyjafjallajökull volcano in April–May 2010 was of modest size but ash was widely dispersed. By combining data from ground surveys and remote sensing we show that the erupted material was 4.8±1.2·1011 kg (benmoreite and trachyte, dense rock equivalent volume 0.18±0.05 km3). About 20% was lava and water-transported tephra, 80% was airborne tephra (bulk volume 0.27 km3) transported by 3–10 km high plumes. The airborne tephra was mostly fine ash (diameter <1000 µm). At least 7·1010 kg (70 Tg) was very fine ash (<28 µm), several times more than previously estimated via satellite retrievals. About 50% of the tephra fell in Iceland with the remainder carried towards south and east, detected over ~7 million km2 in Europe and the North Atlantic. Of order 1010 kg (2%) are considered to have been transported longer than 600–700 km with <108 kg (<0.02%) reaching mainland Europe.

The 2014-2015 Bárðarbunga-Veiðivötn fissure eruption at Holuhraun produced about 1.5 km 3 of lava, making it the largest eruption in Iceland in more than 200 years. Over the course of the eruption, daily volcanic sulfur dioxide (SO 2 ) emissions exceeded daily SO 2 emissions from all anthropogenic sources in Europe in 2010 by at least a factor of 3. We present surface air quality observations from across Northern Europe together with satellite remote sensing data and model simulations of volcanic SO 2 for September 2014. We show that volcanic SO 2 was transported in the lowermost troposphere over long distances and detected by air quality monitoring stations up to 2750 km away from the source. Using retrievals from the Ozone Monitoring Instrument (OMI) and the Infrared Atmospheric Sounding Interferometer (IASI), we calculate an average daily SO 2 mass burden of 99 ± 49 kilotons (kt) of SO 2 from OMI and 61 ± 18 kt of SO 2 from IASI for September 2014. This volcanic burden is at least a factor of 2 greater than the average SO 2 mass burden between 2007 and 2009 due to anthropogenic emissions from the whole of Europe. Combining the observational data with model simulations using the United Kingdom Met Office's Numerical Atmospheric-dispersion Modelling Environment model, we are able to constrain SO 2 emission rates to up to 120 kilotons per day (kt/d) during early September 2014, followed by a decrease to 20-60 kt/d between 6 and 22 September 2014, followed by a renewed increase to 60-120 kt/d until the end of September 2014. Based on these fluxes, we estimate that the eruption emitted a total of 2.0 ± 0.6 Tg of SO 2 during September 2014, in good agreement with ground-based remote sensing and petrological estimates. Although satellite-derived and model-simulated vertical column densities of SO 2 agree well, the model simulations are biased low by up to a factor of 8 when compared to surface observations of volcanic SO 2 on 6-7 September 2014 in Ireland. These biases are mainly due to relatively small horizontal and vertical positional errors in the simulations of the volcanic plume occurring over transport distances of thousands of kilometers. Although the volcanic air pollution episodes were transient and lava-dominated volcanic eruptions are sporadic events, the observations suggest that (i) during an eruption, volcanic SO 2 measurements should be assimilated for near real-time air quality forecasting and (ii) existing air quality monitoring networks should be retained or extended to monitor SO 2 and other volcanic pollutants.

[1] The fragmentation process and aerodynamic behavior of ash from the Eyjafjallajökull eruption of 2010 are investigated by combining grain-size, Scanning Electron Microscopy (SEM), and quantitative particle morphology. Ash samples were collected on land in Iceland at 3-55 km distance from the volcanic vent, and represent various phases of the pulsating eruption. The grain size is fine even for deposits close to the vent, suggesting that the parent particle population at fragmentation consisted of a substantial amount of fine ash. SEM investigation reveals that ash produced during the first phase of the eruption consists of juvenile glass particles showing key features of magma-water interaction, suggesting that phreatomagmatism played a major role in the fragmentation of a vesicle-poor magma. In the last phase of the eruption, fragmentation was purely magmatic and resulted from stress-induced reaction of a microvesicular, fragile melt. The shape of ash, as determined by quantitative morphology analysis, is highly irregular, rendering the settling velocity quite low. This makes transportation by wind much easier than for other more regularly shaped particles of sedimentary origin. We conclude that the combination of magma's fine brittle fragmentation and irregular particle shape was the main factor in the extensive atmospheric circulation of ash from the mildly energetic Eyjafjallajökull eruption.

The 2010 Eyjafjallajökull lasted 39 days and had 4 different phases, of which the first and third (14–18 April and 5–6 May) were most intense. Most of this period was dominated by winds with a northerly component that carried tephra toward Europe, where it was deposited in a number of locations and was sampled by rain gauges or buckets, surface swabs, sticky‐tape samples and air filtering. In the UK, tephra was collected from each of the Phases 1–3 with a combined range of latitudes spanning the length of the country. The modal grain size of tephra in the rain gauge samples was 25 μm, but the largest grains were 100 μm in diameter and highly vesicular. The mass loading was equivalent to 8–218 shards cm−2, which is comparable to tephra layers from much larger past eruptions. Falling tephra was collected on sticky tape in the English Midlands on 19, 20 and 21st April (Phase 2), and was dominated by aggregate clasts (mean diameter 85 μm, component grains <10 μm). SEM‐EDS spectra for aggregate grains contained an extra peak for sulphur, when compared to control samples from the volcano, indicating that they were cemented by sulphur‐rich minerals e.g. gypsum (CaSO4⋅H2O). Air quality monitoring stations did not record fluctuations in hourly PM10 concentrations outside the normal range of variability during the eruption, but there was a small increase in 24‐hour running mean concentration from 21–24 April (Phase 2). Deposition of tephra from Phase 2 in the UK indicates that transport of tephra from Iceland is possible even for small eruption plumes given suitable wind conditions. The presence of relatively coarse grains adds uncertainty to concentration estimates from air quality sensors, which are most sensitive to grain sizes <10 μm. Elsewhere, tephra was collected from roofs and vehicles in the Faroe Islands (mean grain size 40 μm, but 100 μm common), from rainwater in Bergen in Norway (23–91 μm) and in air filters in Budapest, Hungary (2–6 μm). A map is presented summarizing these and other recently published examples of distal tephra deposition from the Eyjafjallajökull eruption. It demonstrates that most tephra deposited on mainland Europe was produced in the highly explosive Phase 1 and was carried there in 2–3 days.

This study examines the sensitivity of atmospheric dispersion model forecasts of volcanic ash clouds to the physical characteristics assigned to the particles. We show that the particle size distribution (PSD) used to initialise a dispersion model has a significant impact on the forecast of the mass loading of the ash particles in the atmosphere. This is because the modeled fall velocity of the particles is sensitive to the particle diameter. Forecasts of the long-range transport of the ash cloud consider particles with diameters between 0.1 μm and 100 μm. The fall velocity of particles with diameter 100 μm is over 5 orders of magnitude greater than a particle with diameter 0.1 μm, and 30 μm particles fall 88% slower and travel up to 5× further than a 100 μm particle. Identifying the PSD of the ash cloud at the source, which is required to initialise a model, is difficult. Further, aggregation processes are currently not explicitly modeled in operational dispersion models due to the high computational costs associated with aggregation schemes. We show that using a modified total grain size distribution (TGSD) that effectively accounts for aggregation processes improves the modeled PSD of the ash cloud and deposits from the eruption of Eyjafjallajökull in 2010. Knowledge of the TGSD of an eruption is therefore critical for reducing uncertainty in quantitative forecasts of ash cloud dispersion. The density and shape assigned to the model particles have a lesser but still significant impact on the calculated fall velocity. Accounting for the density distribution and sphericity of ash from the eruption of Eyjafjallajökull in 2010, modeled particles can travel up to 84% further than particles with default particle characteristics that assume the particles are spherical and have a fixed density.