No abstract

No abstract

No abstract

To investigate the multiaxial fatigue properties of vulcanized natural rubber (NR), a series of tests including both proportional and non‐proportional loading paths on small specimens were performed. The existing fatigue life prediction approaches are evaluated with life data obtained in the tests. It is shown that the equivalent strain approach presents a good prediction of the fatigue life although it has a certain shortcoming. Compared with the strain energy density (SED) model, the cracking energy density (CED) model represents the portion of SED that is available to be released by virtue of crack growth on a given material plane, so it gives better results in the life prediction. Some of the approaches based on critical plane which are widely used for metal fatigue are also tested in this paper, and the results show that the Chen‐Xu‐Huang (CXH) model gives a better prediction, compared with the Smith‐Watson‐Topper (SWT) and Wang–Brown (WB) model. A modified Fatemi–Socie's model has also been introduced, and the results show that the modified model can be used to predict the fatigue life of rubber material well.

Particle-filled elastomers often exhibit a reduction in peak stress after the initial extension under cyclic straining, a phenomenon known as the Mullins effect. In reported literature, long rest periods and elevated temperatures are often necessary conditions to even partially restore stiffness. The stress softening of the polymer nanoparticle composite discussed in this article appeared to be completely reversible in a comparatively short time span (less than 17 h) at room temperature. Although this material acted elastomeric at slow strain rates, significant stiffening, and a pronounced yielding behavior was observed during the first strain cycle at higher strain rates. Subsequent cycling of the material revealed much softer behavior and an absence of the yielding phenomenon, although relatively short rest periods allowed the material to regain its original behavior. The Mullins effect recovery phenomenon was investigated by introducing rest periods of various durations following loading and unloading cycles. Both single and multiple loadings were used in the tests conducted to evaluate recovery. A mechanism of stress recovery was proposed based on the reduction of entanglements and weakening particle-matrix interactions. New entanglements and particle-chain interactions were considered major contributors to the recovery of the stiffness.