When it comes to air pollution complaints, odours are often the most significant contributor. Sources of odour emissions range from natural to anthropogenic. Mitigation of odour can be challenging, multifaceted, site-specific, and is often confounded by its complexity—defined by existing (or non-existing) environmental laws, public ordinances, and socio-economic considerations. The objective of this paper is to review and summarise odour legislation in selected European countries (France, Germany, Austria, Hungary, the UK, Spain, the Netherlands, Italy, Belgium), North America (the USA and Canada), and South America (Chile and Colombia), as well as Oceania (Australia and New Zealand) and Asia (Japan, China). Many countries have incorporated odour controls into their legislation. However, odour-related assessment criteria tend to be highly variable between countries, individual states, provinces, and even counties and towns. Legislation ranges from (1) no specific mention in environmental legislation that regulates pollutants which are known to have an odour impact to (2) extensive details about odour source testing, odour dispersion modelling, ambient odour monitoring, (3) setback distances, (4) process operations, and (5) odour control technologies and procedures. Agricultural operations are one specific source of odour emissions in rural and suburban areas and a model example of such complexities. Management of agricultural odour emissions is important because of the dense consolidation of animal feeding operations and the advance of housing development into rural areas. Overall, there is a need for continued survey, review, development, and adjustment of odour legislation that considers sustainable development, environmental stewardship, and socio-economic realities, all of which are amenable to a just, site-specific, and sector-specific application.
The measurement of odors from wastewater treatment facilities is usually a requirement for compliance monitoring, planning, site expansion, and review of operational practices. These odor measurements are often focused on the "front end" of the facility, i.e. head works, primaries, and aeration processes. Sometimes attention is also placed on digesters and dewatering processes. However, the odor of the biosolids material is often overlooked as a parameter in decision-making at the wastewater treatment facility.
A standard method for measuring and quantifying odour in the ambient air utilizes a portable odour detecting and measuring device known as a field olfactometer (US Public Health Service Project Grant A-58-541). The field olfactometer dynamically dilutes the ambient air with carbon-filtered air in distinct ratios known as "Dilutions-to-Threshold" dilution factors (D/Ts), i.e. 2, 4, 7, 15, etc. Thirteen US states and several cities in North America currently utilize field olfactometry as a key component of determining compliance to odour regulations and ordinances. A controlled environmental chamber was utilized, with hydrogen sulfide as the known test odorant. A hydrogen sulfide environment was created in this controlled chamber using an Advanced Calibration Designs, Inc. Cal2000 Hydrogen Sulfide Generator. The hydrogen sulfide concentration inside the chamber was monitored using an Arizona Instruments, Inc. Jerome Model 631 H2S Analyzer. When the environmental chamber reached a desired test concentration, test operators entered the chamber. The dilution-to-threshold odour concentration was measured using a Nasal Ranger Field Olfactometer (St Croix Sensory, Inc.) and a Barnebey Sutcliffe Corp. Scentometer. The actual hydrogen sulfide concentration was also measured at the location in the room where the operators were standing while using the two types of field olfactometers. This paper presents a correlation between dilution-to-threshold values (D/T) and hydrogen sulfide ambient concentration. For example, a D/T of 7 corresponds to ambient H2S concentrations of 5.7-15.6 microg/m3 (4-11 ppbv). During this study, no significant difference was found between results obtained using the Scentometer or the Nasal Ranger (r = 0.82). Also, no significant difference was found between results of multiple Nasal Ranger users (p = 0.309). The field olfactometers yielded hydrogen sulfide thresholds of 0.7-3.0 microg/m3 (0.5-2.0 ppbv). Laboratory olfactometry yielded comparable thresholds of 0.64-1.3 microg/m3 (0.45-0.9 ppbv). These thresholds are consistent with published values.
The Missouri Air Conservation Commission regulations include regulations that limit the amount of acceptable odor from confined animal feeding operations (CAFOs). The regulations concerning odor designate the use of a scentometer as a screening tool. The rules dictate that if an odor is detectable by an investigator at a dilution ratio of 5.4 using a scentometer then an air sample should be collected and sent to an olfactometry laboratory for an odor panel to determine the detection threshold and the intensity of the odor sample. The detection thresholds are determined following ASTM E679-91 and EN13725. The intensity is determined following ASTM E544-99. If the olfactometry laboratory determined the detection threshold of the sample to be above seven, then the CAFO would be in violation. If the olfactometry laboratory determined the intensity level to be above a level equivalent to 225 ppm of n-butanol, then the source of odor would be in violation. The CAFO odor rules came under scrutiny by representatives of the largest hog producer in the State of Missouri. Specifically, they argued that the detection threshold limit of seven in the CAFO portion of the rule was too low for the rule to realistically identify a violation. This paper presents the results of a study to find the appropriate regulatory level of odor as determined by laboratory olfactometry. The study took place from November 2001 to October 2002. Samples were collected from field locations that exhibited odor produced by confined animal feeding operations and from areas exhibiting no apparent odor. The odors were categorized based upon the scentometer level at which the odors were detectable, and then samples were sent to an odor evaluation laboratory for analysis by olfactometry.
Olfactometry is a precise testing method. How precise depends on the quality assurance / quality control (QA/QC) statistics associated with the laboratory's results. The European Olfactometry testing standard, EN13725:2003, provides a formalized method for monitoring the performance of panel members (assessors) and test results. This is accomplished through testing with the standard odorant 1-butanol (n-butanol).Olfactometry precision can be understood through four different variance values: 1. specific panel variance, 2. within panel variance, 3. inter-panel variance, and 4. inter-laboratory variance.Inter-laboratory studies have shown standard deviation of log threshold values as high as 0.30 and individual laboratories have shown inter-panel standard deviations of 0.10 and within panel standard deviations as low as 0.05. This paper defines the four types of variances and shows how the precision of odor panel results can be expressed as analogous to a group of assessors determining sound level within ±1dB in 95% of the cases. This paper will present these different measures of precision with test data and examples of applications of how this information can be utilized by various stakeholders.
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