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Due to its outstanding electrical characteristics, such as the low temperature expansion coefficient, low dielectric constant and good mechanical properties, cordierite, 2MgO⋅2Al 2 O 3 ⋅ 5SiO 2 , is a very attractive high-temperature ceramic material. In order to accelerate the process of sintering, 2.50 mass% Bi 2 O 3 has been added to the starting mixtures. Liquid phase sintering caused by the presence of bismuth-oxide lowers the temperature of cordierite formation. The mechanical activation of the starting mixtures (0-56 min in vibro-mill) additionally lowers sintering temperatures. The sintering process was performed at 1200, 1300, 1350 and 1400°C, for 2 h. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders and sintered materials was analyzed by the X-ray diffraction method. Furthermore, scanning electron microscopy (SEM) was used in the analysis of the powder morphology.
Y3Al5O12 doped with 0.8%wt.Nd (Nd:YAG) single crystals were grown by the Czochralski technique under an argon atmosphere. The conditions for growing the Nd:YAG single crystals were calculated by using a combination of Reynolds and Grashof numbers. The critical crystal diameter and the critical rate of rotation were calculated from the hydrodynamics of the melt. The crystal diameter Dc=1.5 cm remained constant during the crystal growth while the critical rate of rotation changed from ?c=38 rpm after necking to ?c=13 rpm at the end of the crystal. The value of the rate of crystal growth was experimentally found to be 0.8?1.0 mm/h. According to our previous experiments, it was confirmed that 20 min exposure to conc. H3PO4 at 603 K was suitable for chemical polishing. Also, one-hour exposure to conc. H3PO4 at 493 K was found to be suitable for etching. The lattice parameter a=1.201 (1) nm was determined by X-ray powder diffraction. The obtained results are discussed and compared with published data.
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