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Summary Metal availability in soils is strongly related with sorption processes and the possible association of the metal ions with a particular particle‐size fraction. Therefore, studies of metal retention by a soil will be aided if retention by different size fractions is also studied. Sorption of copper on a calcareous soil and its textural fractions was studied in batch assays. The soil was amended over 3 years with two agroindustrial residues, a composted olive mill sludge and vinasse. Sorption of Cu on the calcareous soil was very large (110 mmol kg−1) and was enhanced by both amendments. Metal retention by the clay fraction of the unamended soil was less than that of the whole soil, but increased dramatically after amendment with olive mill sludge. This was caused by the larger calcite content in this fraction as well as the increase in organic matter content. The amount of Cu sorbed was very large in the silt fraction, again because of the carbonate content of this fraction (300–460 g kg−1). Copper sorption decreased dramatically after removal of carbonate. Copper retention tended to be enhanced by organic amendments. This was particularly evident in the silt fraction, as a consequence of the organic matter accumulation in this fraction. Copper sorption on the calcareous soil and its silt fractions (unamended and amended) was irreversible. By contrast, desorption was measurable from all the carbonate‐free samples (both whole soil and textural fractions), although in all cases a large hysteresis was observed. We conclude that carbonate was the main component responsible for the lack of reversibility.

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An exhaustive validation of operational ocean forecast products available in the Gibraltar Strait and the Alboran Sea is presented. The skill of two ocean model solutions (i.e. the regional CMEMS IBI and the local PdE SAMPA ones) in reproducing the complex surface dynamics in the above areas is evaluated. To this aim, in-situ measurements from 35 drifter buoys (the MEDESS-GIB database) are used as observational reference. A Lagrangian separation distance and a skill score have been applied to evaluate the performance of the modeling systems in reproducing the observed trajectories. Furthermore, the SST validation with in-situ data is carried out by means of validating the model solutions with L3 satellite SST products. The IBI products are evaluated in an extended domain, beyond the Alboran Sea, covering western Mediterranean waters. This analysis reveals some strengths of the regional solution (i.e. realistic values of the Atlantic Jet in the Strait, realistic simulation of the Algerian Current), together with some shortcomings (the major one related to the simulated geographical position and intensity of the Alboran Gyres, particularly the western one). On the other hand, the SAMPA system shows a more accurate model performance and it realistically reproduces the observed surface circulation in the area. The results reflect the effectiveness of the dynamical downscaling performed through the SAMPA system with respect to the regional IBI solution (in which SAMPA is nested), providing an objective measure of the potential added values introduced by the SAMPA downscaling solution in the Alboran Sea.

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