Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability1. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program2,3 found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO2) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 MJ) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. 4). The most plausible way of generating SO2 in such an atmosphere is through photochemical processes5,6. Here we show that the SO2 distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations7 with NIRSpec PRISM (2.7σ)8 and G395H (4.5σ)9. SO2 is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H2S) is destroyed. The sensitivity of the SO2 feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO2 also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

e present an ab initio study of the rovibronic spectra of sulphur monoxide using internally contracted multireference configuration interaction (ic-MRCI) method using aug-cc-pV5Z basis sets. It covers 13 lowest electronic...

Modelling the red-blue asymmetries seen in the broad emission lines of core-collapse supernovae (CCSNe) is a powerful technique to quantify total dust mass formed in the ejecta at late times (>5 years after outburst) when ejecta dust temperatures become too low to be detected by mid-IR instruments. Following our success in using the Monte Carlo radiative transfer code damocles to measure the dust mass evolution in SN 1987A and other CCSNe, we present the most comprehensive sample of dust mass measurements yet made with damocles, for CCSNe aged between four and sixty years after outburst. Our sample comprises of multi-epoch late-time optical spectra taken with the Gemini GMOS and VLT X-Shooter spectrographs, supplemented by archival spectra. For the fourteen CCSNe that we have modelled, we confirm a dust mass growth with time that can be fit by a sigmoid curve which is found to saturate beyond an age of ∼30 years, at a mass of 0.23$^{+0.17}_{-0.12}$ M⊙. An expanded sample including dust masses found in the literature for a further eleven CCSNe and six CCSN remnants, the dust mass at saturation is found to be 0.42$^{+0.09}_{-0.05}$ M⊙. Uncertainty limits for our dust masses were determined from a Bayesian analysis using the affine invariant Markov Chain Monte Carlo ensemble sampler emcee with damocles. The best-fitting line profile models for our sample all required grain radii between 0.1 and 0.5 μm. Our results are consistent with CCSNe forming enough dust in their ejecta to significantly contribute to the dust budget of the Universe.

Multiphoton excitation promises opportunities for opening new photochemical reaction pathways and controlling photoproduct distributions. We demonstrate photonic control of the 6π photocyclization of ortho-terphenyl to make 4a,4b-dihydrotriphenylene (DHT). Using pump–repump–probe spectroscopy we show that 1 + 1′ excitation to a high-lying reactant electronic state generates a metastable species characterized by a red absorption feature that accompanies a repump-induced depletion in the one-photon trans-dihydro product (trans-DHT); signatures of the new photoproduct are clearer for a structural analogue of the reactant that is sterically inhibited against one-photon cyclization. Quantum-chemical computations support assignment of this species to cis-DHT, which is accessible photochemically along a disrotatory coordinate from high-lying electronic states reached by 1 + 1′ excitation. We use time-resolved spectroscopy to track photochemical dynamics producing cis-DHT. In total, we demonstrate that selective multiphoton excitation opens a new photoreaction channel in these photocyclizing reactants by taking advantage of state-dependent correlations between reactant and product electronic states.

We report the preferential nucleation and synthesis of β-FeSi2 nanostructures at pinned step bunches on the Si(111) surface. The nanostructures are synthesized by depositing Fe on Si at room temperature and subsequent annealing. The surface topography is studied using scanning tunneling microscopy and atomic force microscopy. The size, shape and orientation of the nanostructures indicate that the phase is the semiconducting β-FeSi2 phase.