Fly ash based geopolymer is an emerging alternative binder to cement for making concrete. The cracking, spalling and residual strength behaviors of geopolymer concrete were studied in order to understand its fire endurance, which is essential for its use as a building material. Fly ash based geopolymer and ordinary portland cement (OPC) concrete cylinder specimens were exposed to fires at different temperatures up to 1000 o C, with a heating rate of that given in the International Standards Organization (ISO) 834 standard. Compressive strength of the concretes varied in the range of 39 to 58 MPa. After the fire exposures, the geopolymer concrete specimens were found to suffer less damage in terms of cracking than the OPC concrete specimens. The OPC concrete cylinders suffered severe spalling for 800 and 1000 o C exposures, while there was no spalling in the geopolymer concrete specimens. The geopolymer concrete specimens generally retained higher strength than the OPC concrete specimens. The Scanning Electron Microscope (SEM) images of geopolymer concrete showed continued densification of the microstructure with the increase of fire temperature. The strength loss in the geopolymer concrete specimens was mainly because of the difference between the thermal expansions of geopolymer matrix and the aggregates.
The genetic diversity of Amblyomma variegatum (Fabricius) from four Caribbean islands and five African countries was compared by analyzing the sequences of three gene fragments, two mitochondrial (12SrDNA and D-Loop-DL), and one nuclear (intergenic transcribed spacer 2 [ITS2]). Genetic variability of the ITS2 DNA fragment consisted of only uninformative single nucleotide mutations, and therefore this gene was excluded from further analyses. Mitochondrial gene divergences among African populations and between Caribbean and African populations were very low. Nevertheless, the data suggest that A. variegatum is divided into distinct East and West African groups, the western group including all Caribbean samples. Phylogenetic analyses of the 12SrDNA and DL gene sequences showed that the West African A. variegatum clustered in a well-supported monophyletic clade, distinct from eastern paraphyletic lineages. Sequences of A. variegatum from the Caribbean were embedded in the West African clade, which supports the known West African historical origin for these ticks.
Scaffold
biomaterials are typically applied surgically as reinforcement
for weakened or damaged tissue, acting as substrates on which healing
tissue can grow. Natural extracellular matrix (ECM) materials consisting
mainly of collagen are often used for this purpose, but are anisotropic.
Ovine forestomach matrix (OFM) ECM was exposed to increasing strain
and synchrotron-based SAXS diffraction patterns and revealed that
the collagen fibrils within underwent changes in orientation, orientation
index (a measure of isotropy), and extension. Response to the strain
depended on the direction the collagen fibrils were oriented. When
the ECM was stretched in the direction of collagen fibril orientation,
the fibrils become more oriented and begin to take up the strain immediately
(as shown by the increased d-spacing). Stretch applied
perpendicular to dominant fibril direction caused the fibrils to initially
become less oriented as they were pulled away from the original direction,
and less force was initially transmitted along the length of the fibrils
(i.e., the d-spacing changed less). SAXS analysis
of OFM and the starting raw tissue showed there is no difference in
the structural arrangement of the collagen fibrils. Understanding
the directional structural response of these materials under strain
may influence how surgeons select and place the materials in use.
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