Deposition of hafnium silicate films with various hafnium contents was tried by plasma-enhanced chemical vapor deposition using tetraethoxysilane and a hafnium alkoxide. From x-ray photoelectron spectroscopy, the deposited films are confirmed to be silicate with Hf–O–Si bonds but without any Hf–Si bonds. The permittivity calculated from the capacitance of the accumulation layer increases monotonically with an increase in the hafnium content, whereas the optical band gap energy estimated from vacuum ultraviolet absorption spectra decreases. Similar results were obtained from zirconium silicate films deposited using tetraethoxysilane and a zirconium alkoxide. If we compare the films with the same hafnium or zirconium content, the hafnium silicate exhibits a higher permittivity and a larger band gap energy than the zirconium silicate.

Laser ablative technology was used to prepare monodisperse nanoparticles (4–20 nm in diameter) of lead zirconate titanate (PZT). Laser ablation of a PZT ceramic target in oxygen ambience produced amorphous and irregularly shaped PZT nanoparticles. A subsequent on-line thermal treatment performed on the PZT nanoparticles dispersed in the gas phase brought about compaction and crystallization of the nanoparticles without additional particle growth. It was found that the amorphous nanoparticles began to crystallize above 600 °C, and they became a perovskite structure at 900 °C. The crystallized nanoparticles were then size classified by a differential mobility analyzer to yield monodisperse, highly pure, and single-crystalline PZT nanoparticles.

The technical problem of deriving the full Green functions of the elementary pion fields of the nonlinear sigma model in terms of ancestor amplitudes involving only the flat connection and the nonlinear sigma model constraint is a very complex task. In this paper we solve this problem by integrating, order by order in the perturbative loop expansion, the local functional equation derived from the invariance of the SU(2) Haar measure under local left multiplication. This yields the perturbative definition of the pathintegral over the non-linearly realized SU(2) group.

No abstract