The growth of a thin gold film on a conducting polymer surface from nucleation to formation of a continuous layer with a thickness of several nanometers is investigated in situ with grazing incidence small-angle X-ray scattering (GISAXS). Time resolution is achieved by performing the experiment in cycles of gold deposition on poly(N-vinylcarbazole) (PVK) and subsequently recording the GISAXS data. The 2D GISAXS patterns are simulated, and morphological parameters of the gold film on PVK such as the cluster size, shape, and correlation distance are extracted. For the quantitative description of the cluster size evolution, scaling laws are applied. The time evolution of the cluster morphology is explained with a growth model, suggesting a cluster growth proceeding in four steps, each dominated by a characteristic kinetic process: nucleation, lateral growth, coarsening, and vertical growth. A very limited amount of 6.5 wt % gold is observed to be incorporated inside a 1.2-nm-thick enrichment layer in the PVK film.

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We have studied the thermal behavior of amphiphilic, symmetric triblock copolymers having short, deuterated polystyrene (PS) end blocks and a large poly(N-isopropylacrylamide) (PNIPAM) middle block exhibiting a lower critical solution temperature (LCST) in aqueous solution. A wide range of concentrations (0.1−300 mg/mL) is investigated using a number of analytical methods such as fluorescence correlation spectroscopy (FCS), turbidimetry, dynamic light scattering (DLS), small-angle neutron scattering (SANS), and neutron spin-echo spectroscopy (NSE). The critical micelle concentration is determined using FCS to be 1 μM or less. The collapse of the micelles at the LCST is investigated using turbidimetry and DLS and shows a weak dependence on the degree of polymerization of the PNIPAM block. SANS with contrast matching allows us to reveal the core−shell structure of the micelles as well as their correlation as a function of temperature. The segmental dynamics of the PNIPAM shell are studied as a function of temperature and are found to be faster in the collapsed state than in the swollen state. The mode detected has a linear dispersion in q 2 and is found to be faster in the collapsed state as compared to the swollen state. We attribute this result to the averaging over mobile and immobilized segments.

Voltage source converter (VSC)-based high-voltage direct current (HVDC) and multi-terminal (MT)/DC grid technologies are the new HVDC transmission technologies after ultra-high voltage alternative current (UHVAC) and UHVDC transmission technologies which have been widely used in China. The application of the new technologies has resulted in a rapid increase in the number of schemes in construction and planning worldwide. This has been stimulated by the greater level of functionality available from the VSC technology, which makes it suitable for a wide variety of applications. These include the integration of offshore wind farms, embedded links within AC networks and interconnectors, especially where the AC networks are relatively 'weak'. VSC technology has renewed interest in MT DC systems, which may ultimately lead to wide area DC grids. This study outlines the research and application on MT and DC grids in China with respect to VSC-HVDC key technologies and DC grid key technologies based on the presentation given in the International Workshop on Next Generation Power Equipment held on 23 September 2016 in Xian, China. The briefing details of the VSC-HVDC projects constructed and to be constructed in China are summarised in this study.