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A simple co-precipitation method was developed to synthesize AgFeO2 nanoparticles (NPs) with hexagonal 2H and 3R polytypes coexistence. The ratio of 2H and 3R types in AgFeO2 NPs were regulated by controlling the calcination temperature (300, 400, and 500 °C). Such AgFeO2 NPs were used as heterogeneous catalysts to activate peroxymonosulfate (PMS) for the removal of Orange I (OI) in the water. External water conditions effects and the stability of AgFeO2 NPs were investigated. The catalytic performance of AgFeO2 NPs was found to be significantly enhanced with the increasing content of 2H-AgFeO2. 1O2, O2 •–, SO4 •–, and •OH were identified as the dominating reactive oxygen species (ROSs) participated in the catalytic process. The electron transfer of Ag0/Ag+ and Fe2+/Fe3+ cycles facilitated the decomposition of PMS to generate ROSs. The surface hydroxyl groups (−OH) were regarded as the catalytic active sites. The higher 2H-AgFeO2 content in AgFeO2 NPs promoted the concentration of surface hydroxyl groups (C –OH) and the reactivity of AgFeO2 NPs for PMS activation. Based on theoretical calculations, the 2H-AgFeO2 (004) plane with more Fe sites was more conducive to binding with the −OH compared to the 3R-AgFeO2 (012) plane, ascribed to the stronger adsorption energy and shorter Fe–O bond length between 2H-AgFeO2 and −OH.

Surface defect of nanomaterials is an important physical parameter which significantly influences their physical and chemical performances. In this work, high concentration of surface oxygen vancancies (SOVs) are successfully introduced on {001} facets exposed BiOBr nanosheets via a simple surface modification using polybasic carboxylic acids. The chelation interaction between carboxylic acid anions and Bi3+ results in the weakness of Bi-O bond of BiOBr. Afterwards, under visible-light irradiation, the oxygen atoms would absorb the photo-energy and then be released from the surface of BiOBr, leaving SOVs. The electron spin resonance (ESR), high-resolution transmission electron microscopy (HRTEM), and UV–vis diffuse reflectance spectra (DRS) measurements confirm the existence of SOVs. The SOVs can enhance the absorption in visible light region and improve the separation efficiency of photo-generated charges. Hence, the transformation rate of adsorbed O2 on the as-prepared BiOBr with SOVs to superoxide anion radicals (•O2−) and the photocatalytic activity are greatly enhanced. Based on the modification by several carboxylic acids and the photocatalytic results, we propose that carboxylic acids with natural bond orbital (NBO) electrostatic charges absolute values greater than 0.830 are effective in modifying BiOBr.

In conclusion, TSG produces antidepressant-like effects in mice via enhancement of the hippocampal BDNF system.