We have functionalized core-shell CdSe/ZnS quantum dots (QDs) with a photosensitive monolayer, rendering them solution processable and photopatternable. Upon exposure to ultraviolet radiation, films composed of this material were found to polymerize, forming interconnected arrays of QDs. The photoluminescence properties of the nanocrystal films increased with photocuring. The material was found to be suitable for spin casting and was used as the active layer in a green electroluminescent device. The electroluminescence efficiency of devices containing a photocured active layer was found to be largely enhanced when compared to devices containing nonphotocured active layers. The material also showed excellent adhesion to both organic and inorganic substrates because of the unique combination of a siloxane and a photopatternable layer as ligands. The pristine functionalized nanocrystals could easily be used for two-dimensional patterning on organic and inorganic substrates. The photopatternable quantum dots were uniformly dispersed into a photopolymerizable resin to fabricate QD embedded three-dimensional microstructures.
We report an AMOLED fabricated with a solution‐processed indium zinc oxide (IZO) thin‐film transistor (TFT) backplane. The TFT has a bottom gate structure with SiNx gate insulator, spin‐coated IZO active layer, Mo source/drain electrode, and SiO2 passivation layer. The TFT exhibited the field effect mobility of 0.9 cm2/Vs, threshold voltage of 13.6 V, and high on/off current ratio of 1.8e7.
We developed an active matrix organic light‐emitting display(OLED) on a glass using two organic thin‐film transistors(OTFTs) and a capacitor in a pixel. The OTFTs has bottom contact structure with a unique gate insulator and pentacene for the active layer. The width and length of the switching OTFT is 500 μm and 10 μm respectively and the driving OTFT has 900 μm channel width with the same channel length. The characteristics of the OTFTs were examined by test cells around display area and generated images on the panel. The mobility was 0.3 cm2V−1S−1 and the current on/off ratio was 106. The uniformity and stability were confirmed through still and moving images on the panel. The organic light‐emitting layers were fabricated by shadow mask process and color fluorescence materials were used for the emitting layers. The resolution of the panel is 64×RGB×64 in 4.5 inch diagonal and the aperture ratio was 25%.
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