We report on the manufacturing, reliability, and optical functionality of multimode optical waveguide devices developed with a fast processable optical grade silicone. The materials show proven optical losses of <0.05 dB/cm @ 850 nm, surviving >2000 hours 85°C/85% relative humidity testing as well as >4 cycles of wave solder reflow. Fabrication speeds of <10 minutes are shown for a full waveguide stack.Step index 50×50 m waveguides were fabricated and passively MT connectorized on rigid FR4 and flexible polyimide substrates with precise alignment features (cut by dicing saw or ablated by UV laser). Two out-of-plane coupling techniques were demonstrated in this paper, a MT connectorized sample with a 45° turning lens as well as 45° dielectric mirrors on waveguides by dicing saw. Multiple connections between fiber and polymer waveguides with MPO and two out-of-plane coupling techniques in a complete optical link are demonstrated @ 10 Gbps data rates with commercial transceiver modules. Also, complex waveguide geometries such as turnings and crossings are demonstrated by QSFP + transceiver. The eye diagram analyses show comparable results in functionality between silicone waveguide and fiber formats.