Acyclic diene metathesis polymerization: History, methods and applications

Silva, Lucas Caire da; Rojas, Giovanni; Schülz, Michael; Wagener, Kenneth B.

doi:10.1016/j.progpolymsci.2016.12.001

Cited by 96 publications

(67 citation statements)

References 216 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Although ADMET polymerization is a useful technique for synthesizing MOF-forming polymers, because it produces large polymers with precise alkyl spacings between H 2 bdc, the method lacks control over degree of polymerization and it is generally not ideal for making block copolymers 48. Therefore, fractionation by automated silica gel column chromatography was used to characterize the components of the block copolymer ester ligands.…”

Section: Resultsmentioning

confidence: 99%

Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

2019

View full text Add to dashboard Cite

show abstract

Section: Resultsmentioning

confidence: 99%

Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

2019

View full text Add to dashboard Cite

show abstract

“…The incorporation of a polymerizable group, the key moiety for monomer design, is basically required for an SAP strategy where compatibility between the polymerization method employed and functional groups is a significant concern. In this regard, metathesis polymerization emerges as a promising candidate due to the ease of operation, high structural integrity and excellent tolerance to functional groups [ 109 , 110 ]. The authors [ 111 ] synthesized the first precision aliphatic polyesters with alternating microstructures by means of CMP.…”

Section: Cross-metathesis Polymerization (Cmp)mentioning

confidence: 99%

Precision Aliphatic Polyesters via Segmer Assembly Polymerization

Zeng

Yang

2018

Molecules

View full text Add to dashboard Cite

Precise structure-property relation of a biodegradable polymer (e.g., aliphatic polyester) is anticipated only if monomer units and chiral centers are arranged in a defined primary sequence as a biomacromolecule. An emerging synthetic methodology, namely segmer assembly polymerization (SAP), is introduced in this paper to reveal the latest progress in polyester synthesis. Almost any periodic polyester envisioned can be synthesized via SAP using a programed linear or cyclic monomer. In this context, the macroscopic properties of a biodegradable polymer are fundamentally determined by microstructural information through a bottom-up approach. It can be highlighted that SAP ideally combines the precision of organic synthesis and the high efficiency of a polymerization reaction. Previously reported strategies including nucleophilic displacement, polyesterification, cross-metathesis polymerization (CMP), ring-opening polymerization (ROP), ring-opening metathesis polymerization (ROMP) and entropy-driven ring-opening metathesis polymerization (ED-ROMP) are critically reviewed in this paper to shed light on precision synthesis of aliphatic polyesters via SAP. Emerging yet challenging, SAP is a paradigm which reflects the convergence of organic and polymer chemistries and is also an efficient pathway to microstructural control. The current status, future challenges and promising trends in this realm are analyzed and discussed in this overview of the state-of-the-art.

show abstract

“…Since its development by Wagener et al, acyclic diene metathesis polymerization (ADMET) has become a valuable tool for the production of polymeric materials with distinctive properties [1][2][3][4][5]. ADMET has the unique capability of synthesizing linear, "precise" polymers, where the functional groups on the polymer backbone are at regular and known intervals [6,7].…”

Section: Introductionmentioning

confidence: 99%

ADMET polymerization in affordable, commercially available, high boiling solvents

et al. 2020

View full text Add to dashboard Cite

Acyclic diene metathesis polymerization is a powerful technique for creating polymers with precise placement of functional groups. However, due to the need to use high vacuum or other methods to remove the volatile ethylene byproduct and drive the reaction forward, traditional solvents are not feasible. Here we demonstrate the use of three cheap, commercially available solvents as a medium for ADMET polymerizations: propylene carbonate, diethyl phthalate, and dioctyl phthalate. We have shown that by using these solvents, we can increase the molecular weights of ADMET-synthesized polyethylene by over 450% as compared to the bulk polymerization as well as reduce polymerization times from 72 h down to 24 and polymerize challenging, solid monomers.

show abstract

Acyclic diene metathesis polymerization: History, methods and applications

Cited by 96 publications

References 216 publications

Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

Precision Aliphatic Polyesters via Segmer Assembly Polymerization

ADMET polymerization in affordable, commercially available, high boiling solvents

Contact Info

Product

Resources

About