In this work, physical and electrical characteristics of atomic-layer-deposited
HfxZr1−xnormalO2
formed using tetrakis-ethyl methylaminohafnium (TEMAHf), tetrakis-ethylmethylaminozirconium (TEMAZr), and ozone are reported. Confirming Zr addition, film densities decrease with increasing Zr content. A slight increase in interfacial layer thickness is observed for
ZrO2
after high-temperature annealing. All films remain smooth and void-free after high-temperature annealing. Tetragonal phase stabilization is observed with increasing Zr content. Carbon impurities are low and independent of Zr content.
HfxZr1−xnormalO2
transistors and capacitors are fabricated for electrical characterization. Well-behaved capacitance–voltage characteristics are observed for all devices. Only a slight increase in gate leakage current is observed as Zr content is increased from
<2%
(HfO2)
to
∼50%
(Hf0.5Zr0.5normalO2)
.
HfxZr1−xnormalO2
devices have
∼50mV
lower threshold voltage than
HfO2
devices. High field mobilities of
HfxZr1−xnormalO2
devices with 50 and 60% Zr content are higher than
HfO2
or
ZrO2
. All these results indicate
HfxZr1−xnormalO2
is a promising dielectric for
SiO2
replacement.