“…13 This material possesses excellent thermal stability as well as strong ionic properties, which make it significant for many applications including the liquid crystal display smart windows, transparent electrodes, and photovoltaic generators. [14][15][16] So far, a variety of chemical and physical techniques, including spray pyrolysis method, 17 radio frequency magnetron sputtering technique, 18 and dip coating, 19 have been used to fabricate the Cd 2 SnO 4 films; however, only the polycrystalline structures of the Cd 2 SnO 4 thin films were observed via these techniques. In general, the crystal structure of the films largely determines the device performance.…”